A new chain-like cadmium(II) coordination polymer containing chains of water molecules

被引:16
|
作者
Lin, X [1 ]
Wang, YQ
Cao, R
Li, F
Bi, WH
机构
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
关键词
D O I
10.1107/S0108270105007274
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The title cadmium(II) polymer, catena-poly[[[ bis(4-aminopyridine-kappa N) aquacadmium(II)]-mu- 1,4-phenylenediacetato-kappa(4) O, O': O '', O'''] dihydrate], {[Cd(C10H8O4)(C5H6N2)(2)(H2O)] center dot 2H(2)O} (n), comprises one-dimensional wave-like chains, in which the Cd atom is coordinated by 1,4-phenylenediacetate and 4-aminopyridine molecules. The 1,4-phenylenediacetate ligands lie about inversion centres. Extensive hydrogen-bonding interactions between the chains lead to a three-dimensional structure. Free water molecules form chains in the structure.
引用
收藏
页码:M292 / M294
页数:3
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