Synthesis and polymerization of poly(N-substituted maleimide) macromonomers

被引：10

作者：

Oishi, T ^{[1
]}

Lee, YK ^{[1
]}

Nakagawa, A ^{[1
]}

Onimura, K ^{[1
]}

Tsutsumi, H ^{[1
]}

机构：

[1] Yamaguchi Univ, Fac Engn, Dept Appl Chem, Yamaguchi 7558611, Japan

来源：

POLYMER JOURNAL | 2001年 / 33卷 / 01期

关键词：

macromonomer maleimide polymer; radical polymerization; glass transition temperature; thermal stability;

D O I：

10.1295/polymj.33.81

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Four new types of poly(N-substituted maleimide) macromonomers (RMI, R=N-substituent, phenyl and cyclohexyl) were synthesized from methacryloyloxyethyl isocyanate (MOI) and oligomaleimides. The obtained macromonomers were polymerized in tetrahydrofuran (THF) tm afford the corresponding polymacromonomers with degradation temperature of 266-272 degreesC in high yields. The radical polymerizations of the macromonomers with styrene (ST) or methyl methacrylate (MMA) were performed in THF at 60 degreesC to give the corresponding copolymers. The obtained copolymers exhibited higher glass transition temperatures than those of poly(ST) and poly(MMA).

引用

页码：81 / 88

页数：8

共 50 条

[21] Controllable Polymerization of N-Substituted β-Alanine N-Thiocarboxyanhydrides for Convenient Synthesis of Functional Poly(β-peptoid)s
Xiao, Ximian
Zhou, Min
Cong, Zihao
Liu, Longqiang
Zou, Jingcheng
Ji, Zhemin
Cui, Ruxin
Wu, Yueming
Zhang, Haodong
Chen, Sheng
Li, Maoquan
Liu, Runhui
CCS CHEMISTRY, 2023, 5 (04): : 994 - 1004
[22] SYNTHESIS AND FREE-RADICAL POLYMERIZATION OF N-SUBSTITUTED CITRACONIMIDES
PYRIADI, TM
MUTAR, EH
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1980, 18 (08) : 2535 - 2541
[23] ANIONIC-POLYMERIZATION OF N-SUBSTITUTED MALEIMIDE .5. A STUDY ON THE KINETIC FEATURES OF ANIONIC-POLYMERIZATION OF N-PHENYLMALEIMIDE
HAGIWARA, T
SHIMIZU, T
UDA, T
HAMANA, H
NARITA, T
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1990, 28 (01) : 185 - 192
[24] Microwave-Assisted Synthesis of N-Substituted Maleimide Derivatives as Exogenous Antioxidant Agents
Rammohan, Aluru
Reddy, Guda Mallikarjuna
Garcia, Jarem Raul
Zyryanov, Grigory V.
Sravya, Gundala
Reddy, Nemallapudi Bakthavatchala
Yuvaraja, Gutha
JOURNAL OF HETEROCYCLIC CHEMISTRY, 2019, 56 (02) : 470 - 476
[25] Synthesis and in Vitro Evaluation of N-Substituted Maleimide Derivatives as Selective Monoglyceride Lipase Inhibitors
Matuszak, Nicolas
Muccioli, Giulio G.
Labar, Geoffray
Lambert, Didier M.
JOURNAL OF MEDICINAL CHEMISTRY, 2009, 52 (23) : 7410 - 7420
[26] Oxidative polymerization of N-substituted carbazoles
Sarac, AS
Sezer, E
Ustamehmetoglu, B
POLYMERS FOR ADVANCED TECHNOLOGIES, 1997, 8 (09) : 556 - 562
[27] THE POLYMERIZATION ENTHALPY OF N-SUBSTITUTED LACTAMS
KOZINA, MP
SKURATOV, SM
DOKLADY AKADEMII NAUK SSSR, 1959, 127 (03): : 561 - 563
[28] RADICAL POLYMERIZATION OF N-SUBSTITUTED METHACRYLAMIDES
ULBRICH, K
KOPECEK, J
EUROPEAN POLYMER JOURNAL, 1976, 12 (03) : 183 - 187
[29] N-SUBSTITUTED MALEIMIDE INACTIVATION OF RESPONSE TO TASTE CELL STIMULATION
MOOSER, G
JOURNAL OF NEUROBIOLOGY, 1976, 7 (05): : 457 - 468
[30] Synthesis and thermal behavior of poly(ethylene oxide) poly (N-substituted urethane)
Kweon, JO
Lee, YK
Noh, ST
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2001, 39 (23) : 4129 - 4138

← 1 2 3 4 5 →