Synthesis and polymerization of poly(N-substituted maleimide) macromonomers

被引：10
|
作者：
Oishi, T [1 ]
Lee, YK [1 ]
Nakagawa, A [1 ]
Onimura, K [1 ]
Tsutsumi, H [1 ]
机构：
[1] Yamaguchi Univ, Fac Engn, Dept Appl Chem, Yamaguchi 7558611, Japan
来源：
POLYMER JOURNAL | 2001年 / 33卷 / 01期
关键词：
macromonomer maleimide polymer; radical polymerization; glass transition temperature; thermal stability;
D O I：
10.1295/polymj.33.81
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Four new types of poly(N-substituted maleimide) macromonomers (RMI, R=N-substituent, phenyl and cyclohexyl) were synthesized from methacryloyloxyethyl isocyanate (MOI) and oligomaleimides. The obtained macromonomers were polymerized in tetrahydrofuran (THF) tm afford the corresponding polymacromonomers with degradation temperature of 266-272 degreesC in high yields. The radical polymerizations of the macromonomers with styrene (ST) or methyl methacrylate (MMA) were performed in THF at 60 degreesC to give the corresponding copolymers. The obtained copolymers exhibited higher glass transition temperatures than those of poly(ST) and poly(MMA).
引用
收藏
页码：81 / 88
页数：8
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