CpRu-Catalyzed O-H Insertion and Condensation Reactions of α-Diazocarbonyl Compounds

被引：72

作者：

Austeri, Martina ^{[1
]}

Rix, Diane ^{[1
]}

Zeghida, Walid ^{[1
]}

Lacour, Jerome ^{[1
]}

机构：

[1] Univ Geneva, Dept Organ Chem, CH-1211 Geneva 4, Switzerland

来源：

ORGANIC LETTERS | 2011年 / 13卷 / 06期

关键词：

HIGHLY ENANTIOSELECTIVE INSERTION; DIAZO-COMPOUNDS; N-H; ASYMMETRIC CYCLOPROPANATION; CARBONYL YLIDES; ALLYL ARYL; CARBENOIDS; ALKENES; BONDS; ETHERIFICATION;

D O I：

10.1021/ol2000815

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[CpRu(CH3CN)(3)][PF6] and dilmine ligands catalyze together the decomposition of alpha-diazocarbonyl compounds leading to O-H insertion and condensation reactions. In comparison with Rh(II) and Cu(I) complexes, the CpRu catalysts produce rapid and often more selective reactions. Promising enantioselectivities are obtained in dioxole syntheses.

引用

页码：1394 / 1397

页数：4

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