Advances in the Enantioselective Metal-catalyzed N-H and O-H Insertion Reactions with Diazocarbonyl Compounds

被引：24
|
作者：
Burtoloso, Antonio C. B. [1 ]
Santiago, Joao V. [1 ]
Bernardim, Barbara [1 ]
Talero, Alexander G. [1 ]
机构：
[1] Univ Sao Paulo, Inst Quim Sao Carlos, BR-13560970 Sao Carlos, SP, Brazil
来源：
CURRENT ORGANIC SYNTHESIS | 2015年 / 12卷 / 05期
基金：
巴西圣保罗研究基金会;
关键词：
Asymmetric catalysis; carbenes; diazocarbonyls; enantioselective; insertion reactions; metal catalysis; DIAZO-COMPOUNDS; DIRHODIUM(II) CARBOXYLATES; ASYMMETRIC-SYNTHESIS; 3-COMPONENT REACTION; CARBENOID INSERTION; EFFICIENT APPROACH; BONDS; DIAZOACETATES; RHODIUM; DIAZOKETONES;
D O I：
10.2174/157017941205150821153658
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Insertion of diazocarbonyl-derived metallocarbenes into X-H bonds (X= H, C, Si, N, O, S, P, Se) has proven to be a very important method for the construction of C-X bonds in organic chemistry. This mini-review provides a brief historical background, mechanistic aspects and a summary of recent breakthroughs in the area of enantioselective metal-catalyzed N-H and O-H insertion reactions.
引用
收藏
页码：650 / 659
页数：10
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