Orthogonal experimental design for optimizing the synthesis of vinyl-tris(2,2,2-trifluoroethoxy)silane

被引：1

作者：

Jiang, Pan ^{[1
]}

Dong, Hong ^{[1
]}

Luan, Wengen ^{[1
]}

Chen, Daowei ^{[2
]}

Zheng, Yunfeng ^{[2
]}

Huang, Liangbing ^{[2
]}

Qu, Zhirong ^{[1
]}

Wu, Chuan ^{[1
]}

机构：

[1] Hangzhou Normal Univ, Key Lab Organosilicon Chem & Mat Technol, Minist Educ, 2318 Yuhangtang Rd,POB 62, Hangzhou 311121, Zhejiang, Peoples R China

[2] Kaihua Synthet Mat Co Ltd, Novel Silicone Res Inst, Kaihua, Peoples R China

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2020年 / 195卷 / 12期

关键词：

Vinyltrichlorosilane; vinyl-tris(2; 2; 2-trifluoroethoxy)silane; alcoholysis; orthogonal experimental design; ALCOHOLYSIS;

D O I：

10.1080/10426507.2020.1782911

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Vinyl-tris(2,2,2-trifluoroethoxy)silane (VTTFEOS) has been prepared by the alcoholysis of vinyltrichlorosilane with 2,2,2-trifluoroethanol, and an orthogonal design method has been used to determine the key factors affecting the yield of the product. Results indicate that the yield is significantly influenced by the molar ratio of the feedstocks and the condensation temperature. VTTFEOS was purified by means of vacuum distillation and its structure was characterized by(1)H,C-13, and(19)F NMR spectrometries, FTIR spectroscopy, and GC-MS. The densities and the refractive indices of VTTFEOS at 20 and 25 degrees C are reported.

引用

页码：965 / 968

页数：4

共 50 条

[21] High temperature behavior of poly[bis(2,2,2-trifluoroethoxy)-phosphazene]
Nakamura, H
Masuko, T
Kojima, M
Magill, JH
MACROMOLECULAR CHEMISTRY AND PHYSICS, 1999, 200 (11) : 2519 - 2524
[22] Improved Preparation of Methyl Bis(2,2,2-trifluoroethoxy)bromophosphonoacetate for the Stereoselective Synthesis of (E)-α-Bromoacrylates
Nakata, Akiko
Kobayashi, Kenichi
Kogen, Hiroshi
CHEMICAL & PHARMACEUTICAL BULLETIN, 2013, 61 (01) : 108 - 110
[23] Preparation of cyclopropanone 2,2,2-trifluoroethoxy hemiacetals via oxyallyl cation
Trmcic, Milena
Vulovic, Bojan
Zlatar, Matija
Saicic, Radomir N.
ARKIVOC, 2024,
[24] NOVEL SYNTHETIC REACTIONS USING BIS(2,2,2-TRIFLUOROETHOXY)TRIPHENYLPHOSPHORANE
KUBOTA, T
MIYASHITA, S
KITAZUME, T
ISHIKAWA, N
JOURNAL OF ORGANIC CHEMISTRY, 1980, 45 (25): : 5052 - 5057
[25] NOVEL SYNTHETIC REACTIONS USING BIS(2,2,2-TRIFLUOROETHOXY)DIORGANOSULFURANES
KITAZUME, T
ISHIKAWA, N
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1980, 53 (07) : 2064 - 2066
[26] PREPARATION OF 2-(2,2,2-TRIFLUOROETHOXY)-1,3-BUTADIENE
TARRANT, P
STUMP, EC
JOURNAL OF ORGANIC CHEMISTRY, 1961, 26 (11): : 4722 - &
[27] 2,2,2-Trifluoroethoxy Aromatic Heterocycles: Hydrolytically Stable Alternatives to Heteroaryl Chlorides
Fisher, Ethan L.
Ende, Christopher W. Am
Humphrey, John M.
JOURNAL OF ORGANIC CHEMISTRY, 2019, 84 (08): : 4904 - 4909
[28] KINETICS OF THERMAL-DEGRADATION OF POLY[BIS(2,2,2-TRIFLUOROETHOXY)PHOSPHAZENE]
ZELDIN, M
JO, WH
PEARCE, EM
MACROMOLECULES, 1980, 13 (05) : 1163 - 1167
[29] THE EFFECT OF FLUROXENE [(2,2,2-TRIFLUOROETHOXY)ETHANE] ON HEME-BIOSYNTHESIS AND DEGRADATION
ZIMAN, MR
BRADSHAW, JJ
IVANETICH, KM
BIOCHEMICAL JOURNAL, 1980, 190 (03) : 571 - 580
[30] SYNTHESIS, CHARACTERIZATION, AND MODIFICATION OF POLY(ORGANOPHOSPHAZENES) WITH BOTH 2,2,2-TRIFLUOROETHOXY AND PHENOXY SIDE-GROUPS
ALLCOCK, HR
KIM, YB
MACROMOLECULES, 1994, 27 (14) : 3933 - 3942

← 1 2 3 4 5 →