Dual Functionalized Cages in Metal-Organic Frameworks via Stepwise Postsynthetic Modification

被引：50

作者：

Li, Baiyan ^{[1
,2
]}

Ma, Dingxuan ^{[1
]}

Li, Yi ^{[1
]}

Zhang, Yiming ^{[1
]}

Li, Guanghua ^{[1
]}

Shi, Zhan ^{[1
]}

Feng, Shouhua ^{[1
]}

Zaworotko, Michael J. ^{[2
,3
]}

Ma, Shengqian ^{[2
]}

机构：

[1] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China

[2] Univ S Florida, Dept Chem, 4202 East Fowler Ave, Tampa, FL 33620 USA

[3] Univ Limerick, Dept Chem & Environm Sci, Limerick, Ireland

来源：

CHEMISTRY OF MATERIALS | 2016年 / 28卷 / 13期

基金：

美国国家科学基金会; 中国博士后科学基金; 中国国家自然科学基金;

关键词：

CARBON-DIOXIDE CAPTURE; ADSORPTION PROPERTIES; MESOPOROUS SILICA; POROUS MATERIALS; PROTECTING GROUP; ACID; CATALYSIS; STRATEGY; CRYSTAL; SITES;

D O I：

10.1021/acs.chemmater.6b01898

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The introduction of bi- or multifunctionality into different cages of metal-organic frameworks (MOFs) has been of great interest because such MOF materials can demonstrate unique properties for various applications. Herein, we report a general strategy for creating different types of functionalized cages in MOFs by exerting control of the size of cage windows. Selective cage decoration was thereby enabled in such a manner that dual functional MOFs with different types of cages and pores can be created. The resultant different pore function MOF, DPF-MOF, is illustrated as a proof of concept in MOF MIL-101-Cr. An intermediate of a cascade reaction was successfully trapped and controlled the desired reaction direction. This DPF-MOF represents a new type of platform that, by trapping intermediates during the reaction processes, enhances our fundamental understanding of reaction chemistry in porous materials.

引用

页码：4781 / 4786

页数：6

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