Tandem modification of metal-organic frameworks by a postsynthetic approach

被引：171
|
作者：
Wang, Zhenqiang [1 ]
Cohen, Seth M. [1 ]
机构：
[1] Univ Calif San Diego, Dept Chem & Biochem, La Jolla, CA 92093 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 25期
关键词：
metals; organic-inorganic hybrid composites; polymers; supramolecular chemistry; zinc;
D O I：
10.1002/anie.200800686
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Figure Presented) More than a one-trick pony: Postsynthetic modification of metal-organic frameworks (MOFs) permits stepwise, "tandem" modification of the lattice. An MOF bearing reactive functional groups can be subjected to a controllable, heterogeneous transformation sequence while retaining its structural integrity and microporosity. This approach allows the synthesis of MOFs bearing multiple functional groups (represented in the scheme by green and pink spheres). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：4699 / 4702
页数：4
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