Modulating Metal-Organic Frameworks To Breathe: A Postsynthetic Covalent Modification Approach

被引：192
|
作者：
Wang, Zhenqiang [1 ]
Cohen, Seth M. [1 ]
机构：
[1] Univ Calif San Diego, Dept Chem & Biochem, La Jolla, CA 92093 USA
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 46期
基金：
美国国家科学基金会;
关键词：
COORDINATION POLYMER; CO2; ADSORPTION; STRUCTURAL TRANSFORMATIONS; SORPTION PROPERTIES; MIL-53; REACTIVITY; BEHAVIOR; MICROCALORIMETRY; THERMODYNAMICS; TRANSITIONS;
D O I：
10.1021/ja907742z
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Postsynthetic covalent modification of a metal-organic framework (MOF) is shown to activate "breathing" behavior upon adsorption of certain gases. The findings reported suggest that chemical modification can be used to trigger, tune, and control the flexibility of MOFs in an unprecedented fashion. By manipulation of MOF breathing and flexibility, the development of new MOFs with selective gas adsorption properties may be realized.
引用
收藏
页码：16675 / +
页数：5
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