Highly active Au-Pd nanoparticles supported on three-dimensional graphene-carbon nanotube hybrid for selective oxidation of methanol to methyl formate

被引：21

作者：

Wang, Ruiyi ^{[1
,2
]}

Wu, Zhiwei ^{[1
]}

Wang, Guofu ^{[1
]}

Qin, Zhangfeng ^{[1
]}

Chen, Chengmeng ^{[3
]}

Dong, Mei ^{[1
]}

Zhu, Huaqing ^{[1
]}

Fan, Weibin ^{[1
]}

Wang, Jianguo ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Shanxi, Peoples R China

[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

[3] Chinese Acad Sci, Inst Coal Chem, Key Lab Carbon Mat, Taiyuan 030001, Shanxi, Peoples R China

来源：

RSC ADVANCES | 2015年 / 5卷 / 56期

基金：

中国国家自然科学基金;

关键词：

FREE AEROBIC OXIDATION; SOLVENT-FREE OXIDATION; BIMETALLIC NANOPARTICLES; OXYGEN REDUCTION; DIMETHYL ETHER; BENZYL ALCOHOL; GOLD; CATALYSTS; BENZALDEHYDE; NANOSHEETS;

D O I：

10.1039/c5ra06025g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Au-Pd nanoparticles supported on graphene-carbon nanotube hybrid exhibit high catalytic activity in selective oxidation of methanol to methyl formate at low temperature, owning to the strong interaction between graphene and Au-Pd as well as the spacing and bridging effect of nanotube inserter on the hybrid three-dimensional structure.

引用

页码：44835 / 44839

页数：5

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