Pd(TFA)2-catalyzed oxidative coupling of anilides with olefins through C-H bond activation under non-acidic conditions

被引：5
|
作者：
Yu, Xiaoli [1 ]
Yao, Wei [1 ]
Wan, Huida [1 ]
Xu, Zhaojun [1 ]
Wang, Dawei [1 ]
机构：
[1] Jiangnan Univ, Sch Chem & Mat Engn, Minist Educ, Key Lab Food Colloids & Biotechnol, Wuxi 214122, Peoples R China
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2016年 / 822卷
基金：
中国国家自然科学基金;
关键词：
Palladium; Non-coordinating anion; Anilides; Non-acidic; Coupling; BIDENTATE-CHELATION ASSISTANCE; UNACTIVATED C(SP(3))-H BONDS; INTERNAL ALKYNES; AROMATIC AMIDES; DIRECTING GROUP; AMBIENT CONDITIONS; ORTHO-ARYLATION; SOLE OXIDANT; BENZAMIDES; ARYL;
D O I：
10.1016/j.jorganchem.2016.08.025
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
C-H bond activation is an important issue. The Pd-catalyzed and non-coordinating anion improved C-H bond activation was realized through the oxidative coupling reaction of anilides with olefins under non-acidic conditions. Additionally, the catalytic activity of palladium catalysts is enhanced by non-coordinating anions, further proving that non-coordinating anion can be used in palladium-involved reactions. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码：100 / 103
页数：4
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