Syntheses and Structures of Nitridorhenium(V) and Nitridotechnetium(V) Complexes with N,N-[(Dialkylamino)(thiocarbonyl)-N′-(2-hydroxyphenyl)benzamidines

被引：6

作者：

Hung Huy Nguyen ^{[1
]}

Thi Nguyet Trieu ^{[1
]}

Abram, Ulrich ^{[2
]}

机构：

[1] Hanoi Univ Sci, Dept Inorgan Chem, Hanoi, Vietnam

[2] Free Univ Berlin, Inst Chem & Biochem, D-14195 Berlin, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2011年 / 637卷 / 10期

关键词：

Rhenium; Technetium; Tridentate benzamidine; Nitrido complexes; Structure analysis; THIOUREA DERIVATIVES; NITRIDO COMPLEXES; TECHNETIUM; RHENIUM; BENZAMIDINES;

D O I：

10.1002/zaac.201100134

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[MNCl2(PPh3)2] complexes (M = Re, Tc) react with N-[(dialkylamino)(thiocarbonyl)]-N'-(2-hydroxyphenyl)benzamidines (H2L1) with formation of neutral, five-coordinate nitrido complexes of the composition [MN(L-1)(PPh3)]. The products have distorted square-pyramidal coordination spheres with each a tridentate, double-deprotonated benzamidine and a PPh3 ligand in their basal planes.

引用

页码：1330 / 1333

页数：4

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