Syntheses and Structures of Nitridorhenium(V) and Nitridotechnetium(V) Complexes with N,N-[(Dialkylamino)(thiocarbonyl)-N′-(2-hydroxyphenyl)benzamidines

被引：6
|
作者：
Hung Huy Nguyen [1 ]
Thi Nguyet Trieu [1 ]
Abram, Ulrich [2 ]
机构：
[1] Hanoi Univ Sci, Dept Inorgan Chem, Hanoi, Vietnam
[2] Free Univ Berlin, Inst Chem & Biochem, D-14195 Berlin, Germany
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2011年 / 637卷 / 10期
关键词：
Rhenium; Technetium; Tridentate benzamidine; Nitrido complexes; Structure analysis; THIOUREA DERIVATIVES; NITRIDO COMPLEXES; TECHNETIUM; RHENIUM; BENZAMIDINES;
D O I：
10.1002/zaac.201100134
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
[MNCl2(PPh3)2] complexes (M = Re, Tc) react with N-[(dialkylamino)(thiocarbonyl)]-N'-(2-hydroxyphenyl)benzamidines (H2L1) with formation of neutral, five-coordinate nitrido complexes of the composition [MN(L-1)(PPh3)]. The products have distorted square-pyramidal coordination spheres with each a tridentate, double-deprotonated benzamidine and a PPh3 ligand in their basal planes.
引用
收藏
页码：1330 / 1333
页数：4
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