Reductive amination of ketones/aldehydes with amines using BH3N(C2H5)3 as a reductant

被引：13

作者：

Zou, Qizhuang ^{[1
]}

Liu, Fei ^{[1
]}

Zhao, Tianxiang ^{[1
]}

Hu, Xingbang ^{[2
]}

机构：

[1] Guizhou Univ, Sch Chem & Chem Engn, Key Lab Green Chem & Clean Energy Technol, Guiyang 550025, Peoples R China

[2] Nanjing Univ, Sch Chem & Chem Engn, Nanjing 210093, Jiangsu, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2021年 / 57卷 / 69期

关键词：

RUTHENIUM NANOPARTICLES; HORSERADISH-PEROXIDASE; MOLECULAR-HYDROGEN; N-FORMYLATION; BORIC-ACID; CATALYST; NMR; CHEMISTRY; CO2;

D O I：

10.1039/d1cc02618f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Herein, we report the first example of efficient reductive amination of ketones/aldehydes with amines using BH3N(C2H5)(3) as a catalyst and a reductant under mild conditions, affording various tertiary and secondary amines in excellent yields. A mechanistic study indicates that BH3N(C2H5)(3) plays a dual function role of promoting imine and iminium formation and serving as a reductant in reductive amination.

引用

页码：8588 / 8591

页数：4

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