Reductive amination of ketones/aldehydes with amines using BH3N(C2H5)3 as a reductant

被引：13
|
作者：
Zou, Qizhuang [1 ]
Liu, Fei [1 ]
Zhao, Tianxiang [1 ]
Hu, Xingbang [2 ]
机构：
[1] Guizhou Univ, Sch Chem & Chem Engn, Key Lab Green Chem & Clean Energy Technol, Guiyang 550025, Peoples R China
[2] Nanjing Univ, Sch Chem & Chem Engn, Nanjing 210093, Jiangsu, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2021年 / 57卷 / 69期
关键词：
RUTHENIUM NANOPARTICLES; HORSERADISH-PEROXIDASE; MOLECULAR-HYDROGEN; N-FORMYLATION; BORIC-ACID; CATALYST; NMR; CHEMISTRY; CO2;
D O I：
10.1039/d1cc02618f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Herein, we report the first example of efficient reductive amination of ketones/aldehydes with amines using BH3N(C2H5)(3) as a catalyst and a reductant under mild conditions, affording various tertiary and secondary amines in excellent yields. A mechanistic study indicates that BH3N(C2H5)(3) plays a dual function role of promoting imine and iminium formation and serving as a reductant in reductive amination.
引用
收藏
页码：8588 / 8591
页数：4
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