Synthesis and Properties of Nano-SiO2/Polysiloxane Modified Polyacrylate Emulsifier-Free Emulsion

被引：30
|
作者：
Zhou, Jianhua [1 ,2 ]
Zhang, Lin [1 ,2 ]
Ma, Jianzhong [1 ,2 ]
机构：
[1] Shaanxi Univ Sci & Technol, Minist Educ, Key Lab Auxiliary Chem & Technol Chem Ind, Xian 710021, Peoples R China
[2] Shaanxi Univ Sci & Technol, Coll Resource & Environm, Xian 710021, Peoples R China
来源：
POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING | 2011年 / 50卷 / 01期
基金：
国家高技术研究发展计划(863计划);
关键词：
Emulsion polymerization; Nano-silica; Polyacrylate; Polysiloxane; Surfmer; CROSS-LINKING; SILICA NANOPARTICLES; LATEX-PARTICLES; POLYMERIZATION; DISPERSION;
D O I：
10.1080/03602559.2010.512343
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Nano-SiO2/polysiloxane modified polyacrylate emulsifier-free emulsion was synthesized by emulsion polymerization using surfmer and the sol-gel process. The cocondensation of trimethoxysilyl groups of the polyacrylate polymer and TEOS formed a cross-linking network film, in which the nanometer-size silica particles were dispersed homogeneously in the acrylic polymer component. The hybrid films were transparent, solvent-resistant, good thermal stability and mechanical properties.
引用
收藏
页码：15 / 19
页数：5
相关论文
共 50 条
  • [41] Thermal properties of poly(methyl methacrylate) prepared by emulsifier-free emulsion polymerization
    B. B. Troitskii
    L. V. Khokhlova
    V. N. Denisova
    M. A. Novikova
    A. E. Golubev
    A. V. Arapova
    Russian Journal of Applied Chemistry, 2007, 80 : 1575 - 1578
  • [42] Thermal properties of poly(metlyl methacrylate) prepared by emulsifier-free emulsion polymerization
    Troitskii, B. B.
    Khokhlova, L. V.
    Denisova, V. N.
    Novikova, M. A.
    Golubev, A. E.
    Arapova, A. V.
    RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2007, 80 (09) : 1575 - 1578
  • [43] Amphoteric initiators suitable for emulsifier-free emulsion polymerization and the properties of the resulting latices
    Fang, SJ
    Fujimoto, K
    Kondo, S
    Shiraki, K
    Kawaguchi, H
    COLLOID AND POLYMER SCIENCE, 2001, 279 (06) : 589 - 596
  • [44] Amphoteric initiators suitable for emulsifier-free emulsion polymerization and the properties of the resulting latices
    S.-J. Fang
    K. Fujimoto
    S. Kondo
    K. Shiraki
    H. Kawaguchi
    Colloid and Polymer Science, 2001, 279 : 589 - 596
  • [45] SYNTHESIS AND CHARACTERIZATION OF MODIFIED EPOXY RESIN/MODIFIED NANO-SiO2 COMPOSITE
    Mo, Zunli
    Pu, Bin
    Meng, Shujuan
    Zhang, Chun
    Xie, Tingting
    Jiang, Caidi
    ADVANCED COMPOSITES LETTERS, 2013, 22 (02) : 25 - 30
  • [46] Synthesis and characterization of emulsifier-free core-shell fluorine-containing polyacrylate latex
    Cui, Xuejun
    Zhong, Shuangling
    Wang, Hongyan
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2007, 303 (03) : 173 - 178
  • [47] Synthesis and Application of Polyacrylate/Nano-SiO2 Composite Leather Finishing Agent with Polymerizable Surfactant
    Liu, Junli
    Ma, Jianzhong
    Bao, Yan
    Zhu, Zhenfeng
    POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING, 2012, 51 (14) : 1460 - 1467
  • [48] Synthesis of Modified Epoxy Resin Undercoat for Resistor by Nano-SiO2
    王秀宇
    张之圣
    李海燕
    胡明
    Transactions of Tianjin University, 2006, (03) : 193 - 198
  • [49] Synthesis of Waterborne Polyurethane Modified by Nano-SiO2 Silicone and Properties of the WPU Coated RDX
    Li Yang
    Zhao Tianbo
    Qu Xiaoling
    Ding Hongjing
    Li Fengyan
    ChinaPetroleumProcessing&PetrochemicalTechnology, 2015, 17 (02) : 39 - 45
  • [50] Synthesis of Waterborne Polyurethane Modified by Nano-SiO2 Silicone and Properties of the WPU Coated RDX
    Li Yang
    Zhao Tianbo
    Qu Xiaoling
    Ding Hongjing
    Li Fengyan
    CHINA PETROLEUM PROCESSING & PETROCHEMICAL TECHNOLOGY, 2015, 17 (02) : 39 - 45
12345