Synthesis and Properties of Nano-SiO2/Polysiloxane Modified Polyacrylate Emulsifier-Free Emulsion

被引：30
|
作者：
Zhou, Jianhua [1 ,2 ]
Zhang, Lin [1 ,2 ]
Ma, Jianzhong [1 ,2 ]
机构：
[1] Shaanxi Univ Sci & Technol, Minist Educ, Key Lab Auxiliary Chem & Technol Chem Ind, Xian 710021, Peoples R China
[2] Shaanxi Univ Sci & Technol, Coll Resource & Environm, Xian 710021, Peoples R China
来源：
POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING | 2011年 / 50卷 / 01期
基金：
国家高技术研究发展计划(863计划);
关键词：
Emulsion polymerization; Nano-silica; Polyacrylate; Polysiloxane; Surfmer; CROSS-LINKING; SILICA NANOPARTICLES; LATEX-PARTICLES; POLYMERIZATION; DISPERSION;
D O I：
10.1080/03602559.2010.512343
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Nano-SiO2/polysiloxane modified polyacrylate emulsifier-free emulsion was synthesized by emulsion polymerization using surfmer and the sol-gel process. The cocondensation of trimethoxysilyl groups of the polyacrylate polymer and TEOS formed a cross-linking network film, in which the nanometer-size silica particles were dispersed homogeneously in the acrylic polymer component. The hybrid films were transparent, solvent-resistant, good thermal stability and mechanical properties.
引用
收藏
页码：15 / 19
页数：5
相关论文
共 50 条
  • [1] Synthesis and Characterization of nano-SiO2 modified fluorine-containing polyacrylate emulsifier-free emulsion
    Zhou, Jianhua
    Chen, Xin
    Duan, Hao
    Ma, Jianzhong
    Ma, Yurong
    APPLIED SURFACE SCIENCE, 2015, 331 : 504 - 511
  • [2] Synthesis and characterization of organic fluorine and nano-SiO2 modified polyacrylate emulsifier-free latex
    Zhou, Jianhua
    Chen, Xin
    Duan, Hao
    Ma, Jianzhong
    PROGRESS IN ORGANIC COATINGS, 2015, 89 : 192 - 198
  • [3] Synthesis and application of emulsifier-free emulsion polymerization for acrylic resin/nano-SiO2 leather finishing agent
    Hu Jing
    Ma Jianzhong
    7th Asian International Conference of Leather Science and Technology Sect 1 and 2, 2006, : 161 - 169
  • [4] Synthesis of fluorinated emulsifier-free polyacrylate emulsion in the presence of polymerizable emulsifier
    Xiao, Xin-Yan
    Wang, Ye
    Wan, Cai-Xia
    Huanan Ligong Daxue Xuebao/Journal of South China University of Technology (Natural Science), 2009, 37 (09): : 133 - 138
  • [5] An emulsifier-free core-shell polyacrylate/diacetone acrylamide emulsion with nano-SiO2 for room temperature curable waterborne coatings
    Wang, Rong-Min
    Lv, Wei-Hua
    He, Yu-Feng
    Wang, Yan
    Guo, Jun-Feng
    POLYMERS FOR ADVANCED TECHNOLOGIES, 2010, 21 (02) : 128 - 134
  • [6] Hybrid polysiloxane/polyacrylate/nano-SiO2 emulsion for waterborne polyurethane coatings
    Jiang, Weibin
    Dai, Anqi
    Zhou, Tao
    Xie, Huasheng
    POLYMER TESTING, 2019, 80
  • [7] The Synthesized of Nano-SiO2 and Silicon Modified Polyacrylate Emulsion
    Hou, Fa Qiu
    Zhao, Yan
    Qing, Ning
    Chen, Yong Jun
    FRONTIERS OF MANUFACTURING AND DESIGN SCIENCE IV, PTS 1-5, 2014, 496-500 : 242 - 245
  • [8] Properties of acrylic resin/nano-SiO2 leather finishing agent prepared via emulsifier-free emulsion polymerization
    Hu, Jing
    Ma, Jianzhong
    Deng, Weijun
    MATERIALS LETTERS, 2008, 62 (17-18) : 2931 - 2934
  • [9] Acrylic emulsifier-free emulsion polymerization containing hydrophilic hydroxyl monomer in the presence or absence of nano-SiO2
    Zhang, Fa-Ai
    Yu, Cai-Li
    EUROPEAN POLYMER JOURNAL, 2007, 43 (04) : 1105 - 1111
  • [10] Effects of Polymerizable Emulsifier on the Properties of Polyacrylate/Nano-SiO2 Leather Finishing Agent
    Ma Jianzhong
    Liu Junli
    Bao Yan
    PROCEEDINGS OF THE 12TH INTERNATIONAL WOOL RESEARCH CONFERENCE, VOLS I AND II, 2010, : 608 - 612
12345