Methane adsorption and methanol desorption of copper modified boron silicate

被引：4

作者：

Wang, Xueting ^{[1
,2
]}

Shishkin, Alexander ^{[1
,2
]}

Hemmingsson, Felix ^{[1
,2
]}

Skoglundh, Magnus ^{[1
,2
]}

Martinez-Casado, Francisco Javier ^{[3
]}

Bock, Lorenz ^{[1
]}

Idstrom, Alexander ^{[1
]}

Nordstierna, Lars ^{[1
]}

Harelind, Hanna ^{[1
,2
]}

Carlsson, Per-Anders ^{[1
,2
]}

机构：

[1] Chalmers Univ Technol, Dept Chem & Chem Engn, S-41296 Gothenburg, Sweden

[2] Chalmers Univ Technol, Competence Ctr Catalysis, S-41296 Gothenburg, Sweden

[3] Lund Univ, MAX Lab 4, S-22100 Lund, Sweden

来源：

RSC ADVANCES | 2018年 / 8卷 / 63期

基金：

瑞典研究理事会;

关键词：

INFRARED-SPECTROSCOPY; NMR-SPECTROSCOPY; OXO-CLUSTERS; OXIDATION; ZEOLITES; FRAMEWORK; REACTIVITY; CONVERSION; CU-SSZ-13; ALUMINUM;

D O I：

10.1039/c8ra08038k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Boron silicate (BS) with a chabazite framework structure was synthesised using a direct route and rigorously characterized before it was ion-exchanged with copper to form Cu-BS. Employing in situ infrared spectroscopy, we show that Cu-BS is capable of oxidising methane to methoxy species and methanol interacts with the boron sites without deprotonation.

引用

页码：36369 / 36374

页数：6

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