Crown-ether annelated dithiadiazafulvalenes

被引：15

作者：

Guérin, D ^{[1
]}

Carlier, R ^{[1
]}

Guerro, M ^{[1
]}

Lorcy, D ^{[1
]}

机构：

[1] Univ Rennes 1, CNRS, UMR 6510, Inst Chim Rennes, F-35042 Rennes, France

来源：

TETRAHEDRON | 2003年 / 59卷 / 28期

关键词：

dithiadiazafulvalene; crown-ether; complexation; redox behavior;

D O I：

10.1016/S0040-4020(03)00767-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthetic approaches towards crown-ether annelated dithiadiazafulvalenes (DTDAF) are described. As evidenced by electrochemistry, the reaction of N,N'-bridged-bisthiazolium salts in basic medium favors the formation of the DTDAF via an intramolecular coupling while the reaction of N,N'-bridged-bisthiazoline selone with trivalent phosphorus derivative leads to the donor core via an intermolecular coupling. The complexation of various metal cations on these crown-ether annelated DTDAF is investigated by electrochemistry. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

页码：5273 / 5278

页数：6

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