[(S,S)-N-({6-[1-(dimethylamino)ethyl]-pyridin-2-yl}ethyl)-N,N-dimethylamine-κ3N]dibromozinc(II)

被引：2
|
作者：
Panosyan, FB [1 ]
Lough, AJ [1 ]
Chin, J [1 ]
机构：
[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2003年 / 59卷
关键词：
D O I：
10.1107/S1600536803018920
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, [ZnBr2(C13H23N3)], (3), was readily prepared from the reaction between ZnBr2 and (S,S)-(1-6-[1-(dimethylamino)ethyl]-2-pyridinylethyl)-N,N-dimethylamine. (3) exists as a distorted square pyramid and crystallizes with two independent molecules in the asymmetric unit. The apical position of the square pyramid is occupied by one of the Br atoms, with the base of the pyramid consisting of the three N atoms of the ligand and the other Br atom. This is the first reported structure determination of a compound containing the C-2-symmetric molecule (S,S)-N-(1-{6-[1-(dimethylamino)ethyl]pyridin-2-yl}ethyl)-N,N-dimethylamine.
引用
收藏
页码：M827 / M829
页数：3
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