Enhanced capacity and significant rate capability of Mn3O4/reduced graphene oxide nanocomposite as high performance anode material in lithium-ion batteries

We report enhanced capacity, significant rate capability of Mn3O4 microsheet and reduced graphene oxide (Mn3O4/rGO) nanocomposite as high performance anode material in lithium ion battery. The Mn3O4/rGO nanocomposite prepared by a facile, low temperature chemical reduction procedure has achieved superior capacity of similar to 677 mAh g(-1) (current rate = 123 mA g(-1)) after 150 charge/discharge cycles (retention = 85%) and appreciable rate capability of 640 mAh g(-1) @1.2 A g(-1). The comparative investigation reveals the distinguished electrochemical performance of Mn3O4/rGO as compared with MnO2/rGO, MnO2 and graphene oxide. Lithium ion diffusion coefficient of Mn3O4/rGO (2.4 x 10(-1) m(2) s(-1)) is higher than MnO2/rGO, MnO2 and graphene oxide that facilitates the smooth passage of Li ions in the composite delivering noticeable electrochemical performance. Mn3O4/rGO is synthesized by the simple chemical reduction of MnO2 nanorod/rGO nanocomposite and the procedure can be extended for the synthesis of other potentially useful, simple/complex metal oxides (varying shape and size) as anode materials in lithium ion batteries.