Postsynthetic Modification of Metal-Organic Frameworks by Vapor-Phase Grafting

被引：13

作者：

Rong, Siyi ^{[1
]}

Chen, Shizheng ^{[1
]}

Su, Pengcheng ^{[1
]}

Tang, Huiyu ^{[1
]}

Jia, Miaomiao ^{[1
]}

Xia, Yan ^{[1
]}

Li, Wanbin ^{[1
]}

机构：

[1] Jinan Univ, Sch Environm, Guangdong Key Lab Environm Pollut & Hlth, Guangzhou 511443, Peoples R China

来源：

INORGANIC CHEMISTRY | 2021年 / 60卷 / 16期

基金：

中国国家自然科学基金;

关键词：

LIGAND-EXCHANGE; GAS-ADSORPTION; FLUORIDE; PERFORMANCE; FABRICATION; UIO-66-NH2; STABILITY; REMOVAL;

D O I：

10.1021/acs.inorgchem.1c00284

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A vapor-phase grafting strategy is developed for the postsynthetic modification of metal-organic frameworks (MOFs). On the basis of the Schotten-Baumann reaction between acyl chloride (-COCl) and amino (-NH2) groups and hydrolysis of -COCl, the carboxylated MOFs could be prepared through simple exposure in vaporized acyl chloride molecules and immersion in water. The modified MOFs have well-maintained crystalline structures and porosities and show substantially improved fluoride removal performance.

引用

页码：11745 / 11749

页数：5

共 50 条

[41] Postsynthetic covalent modification of a neutral metal-organic framework
Wang, Zhenqiang
Cohen, Seth M.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (41) : 12368 - +
[42] PHOTOLUMINESCENCE OF GASB GROWN BY METAL-ORGANIC VAPOR-PHASE EPITAXY
CHIDLEY, ETR
HAYWOOD, SK
HENRIQUES, AB
MASON, NJ
NICHOLAS, RJ
WALKER, PJ
SEMICONDUCTOR SCIENCE AND TECHNOLOGY, 1991, 6 (01) : 45 - 53
[43] GROWTH MECHANISMS IN THE METAL-ORGANIC VAPOR-PHASE EPITAXY OF INP
COVA, P
MASUT, RA
CURRIE, JF
JOURNAL DE PHYSIQUE III, 1992, 2 (12): : 2333 - 2347
[44] Growth behavior of GaSb by metal-organic vapor-phase epitaxy
Rathi, Manish K.
Hawkins, Brian E.
Kuech, Thomas F.
JOURNAL OF CRYSTAL GROWTH, 2006, 296 (02) : 117 - 128
[45] Microscopic and Mesoscopic Dual Postsynthetic Modifications of Metal-Organic Frameworks
Lee, Byeongchan
Moon, Dohyun
Park, Jinhee
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 59 (33) : 13793 - 13799
[46] Vapor-Phase Cyclohexene Epoxidation by Single-Ion Fe(III) Sites in Metal-Organic Frameworks
Otake, Ken-ichi
Ahn, Sol
Knapp, Julia
Hupp, Joseph T.
Notestein, Justin M.
Farha, Omar K.
INORGANIC CHEMISTRY, 2021, 60 (04) : 2457 - 2463
[47] PHOTOASSISTED METAL-ORGANIC VAPOR-PHASE EPITAXY OF ZNTE ON GAAS
DUMONT, H
QUHEN, B
BOUREE, JE
KUHN, W
GOROCHOV, O
THIN SOLID FILMS, 1994, 241 (1-2) : 370 - 373
[48] Postsynthetic Ligand and Cation Exchange in Robust Metal-Organic Frameworks
Kim, Min
Cahill, John F.
Fei, Honghan
Prather, Kimberley A.
Cohen, Seth M.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (43) : 18082 - 18088
[49] Bifunctional metal-organic frameworks afforded by postsynthetic modification for efficient cycloaddition of CO2 and epoxides
Gao, Wei
Wang, Cui-Li
Chen, Le
Zhu, Cai-Yong
Li, Peng
Li, Ji-Yang
Liu, Jie-Ping
Zhang, Xiu-Mei
APPLIED ORGANOMETALLIC CHEMISTRY, 2022, 36 (09)
[50] Ab Initio Study of Hydrostable Metal-Organic Frameworks for Postsynthetic Modification and Tuning toward Practical Applications
Anene, Uchenna A.
Alpay, S. Pamir
ACS OMEGA, 2022, 7 (09): : 7791 - 7805

← 1 2 3 4 5 →