Adsorption behavior and self-aggregation of 5,10,15,20-tetrakis-(4-sulfonatophenyl)-porphyrin on quaternized polysulfone membrane

被引：10
|
作者：
Li, Min [1 ,2 ]
Zhao, Lizhi [1 ,2 ]
Zhang, Yuecong [1 ,2 ]
Liu, Manman [1 ,2 ]
Ye, Hui [1 ,2 ]
Zhang, Yuzhong [1 ,2 ]
Chen, Xi [1 ,2 ]
机构：
[1] Tianjin Polytech Univ, Sch Mat Sci & Engn, Tianjin 300387, Peoples R China
[2] Tianjin Polytech Univ, State Key Lab Hollow Fiber Membrane Mat & Proc, Tianjin 300387, Peoples R China
来源：
COLLOID AND POLYMER SCIENCE | 2015年 / 293卷 / 02期
基金：
中国国家自然科学基金;
关键词：
TPPS; Adsorption; Membrane-TPPS interaction; pK(a); Aggregates; ANION-EXCHANGE MEMBRANES; PORPHYRIN NANORODS; AQUEOUS-SOLUTION; OPTICAL SENSOR; BORON REMOVAL; THIN-FILMS; PH; TETRAKIS(4-SULFONATOPHENYL)PORPHYRIN; WATER; 5,10,15,20-TETRAKIS(4-SULFONATOPHENYL)PORPHYRIN;
D O I：
10.1007/s00396-014-3438-y
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Adsorption of 5,10,15,20-tetrakis-(4-sulfonatophenyl)-porphyrin (TPPS) on the quaternized polysulfone (QAPSF) porous membrane based on the electrostatic interaction was investigated. TPPS species in solution showed different adsorption behavior. The diacid (H4TPPS2-) form of the porphyrin at pH 4.0 showed almost equal adsorption capacity, while slower adsorption rate on the QAPSF membrane, compared with the free-base (H2TPPS4-) form at pH 7.0; J-aggregates of TPPS in aqueous solution affected the adsorption. Compared with in the aqueous solution, the apparent pK (a) for the equilibrium between H4TPPS2- and H2TPPS4- of the adsorbed porphyrin was significantly decreased by the interaction between TPPS and QAPSF. J-type aggregation of TPPS can also occur on the membrane, while much lower pH is required. The pH dependency was considerably influenced by adsorption capacity; higher adsorption capacity was in favor of the protonation and J-aggregation at relative higher pH.
引用
收藏
页码：513 / 522
页数：10
相关论文
共 50 条
  • [1] Adsorption behavior and self-aggregation of 5,10,15,20-tetrakis-(4-sulfonatophenyl)-porphyrin on quaternized polysulfone membrane
    Min Li
    Lizhi Zhao
    Yuecong Zhang
    Manman Liu
    Hui Ye
    Yuzhong Zhang
    Xi Chen
    [J]. Colloid and Polymer Science, 2015, 293 : 513 - 522
  • [2] Aerogels containing 5,10,15,20-tetrakis-(4-sulfonatophenyl)-porphyrin with controlled state of aggregation
    Pablo Pino-Pinto, Juan
    Oyarzun-Ampuero, Felipe
    Orellana, Sandra L.
    Flores, Mario E.
    Nishide, Hiroyuki
    Moreno-Villoslada, Ignacio
    [J]. DYES AND PIGMENTS, 2017, 139 : 193 - 200
  • [3] Self-association of 5,10,15,20-tetrakis-(4-sulfonatophenyl)-porphyrin tuned by poly(decylviologen) and sulfobutylether-β-cyclodextrin
    Flores, Mario E.
    Sano, Naoki
    Araya-Hermosilla, Rodrigo
    Shibue, Toshimichi
    Olea, Andres F.
    Nishide, Hiroyuki
    Moreno-Villoslada, Ignacio
    [J]. DYES AND PIGMENTS, 2015, 112 : 262 - 273
  • [4] Confinement of 5,10,15,20-tetrakis-(4-sulfonatophenyl)-porphyrin in novel poly(vinylpyrrolidone)s modified with aromatic amines
    Gomez-Tardajos, Myriam
    Pablo Pino-Pinto, Juan
    Diaz-Soto, Claudia
    Flores, Mario E.
    Gallardo, Alberto
    Elvira, Carlos
    Reinecke, Helmut
    Nishide, Hiroyuki
    Moreno-Villoslada, Ignacio
    [J]. DYES AND PIGMENTS, 2013, 99 (03) : 759 - 770
  • [5] Controlling the aggregation of 5,10,15,20-tetrakis-(4-sulfonatophenyl)-porphyrin by the use of polycations derived from polyketones bearing charged aromatic groups
    Toncelli, Claudio
    Pablo Pino-Pinto, Juan
    Sano, Naoki
    Picchioni, Francesco
    Broekhuis, Antonius A.
    Nishide, Hiroyuki
    Moreno-Villoslada, Ignacio
    [J]. DYES AND PIGMENTS, 2013, 98 (01) : 51 - 63
  • [6] Unique photoreactivity of mercury(II) 5,10,15,20-tetrakis (4-sulfonatophenyl)porphyrin
    Horváth, O
    Valicsek, Z
    Vogler, A
    [J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2004, 7 (07) : 854 - 857
  • [7] SPECTRAL MANIFESTATIONS OF SPECIFIC SOLVATION OF 5,10,15,20-TETRAKIS-(4-SULFONATOPHENYL)-PORPHYRIN AND ITS DOUBLY PROTONATED FORM IN AQUEOUS SOLUTIONS
    Klimovich, P. G.
    Krylov, A. B.
    Kruk, M. M.
    [J]. JOURNAL OF APPLIED SPECTROSCOPY, 2021, 88 (01) : 19 - 26
  • [8] Spectral Manifestations of Specific Solvation of 5,10,15,20-Tetrakis-(4-Sulfonatophenyl)-Porphyrin and its Doubly Protonated Form in Aqueous Solutions
    P. G. Klimovich
    A. B. Krylov
    M. M. Kruk
    [J]. Journal of Applied Spectroscopy, 2021, 88 : 19 - 26
  • [9] J- and H-Aggregation of 5,10,15,20-Tetrakis-(4-sulfonatophenyl)porphyrin within Stimuli Responsive Complex Micelles via Electrostatic Interaction
    Yu, Qingyuan
    Wu, Chenglin
    Wang, Fang
    [J]. ASIAN JOURNAL OF CHEMISTRY, 2014, 26 (14) : 4269 - 4272
  • [10] Aggregation and supramolecular chirality of 5,10,15,20-tetrakis-(4-sulfonatophenyl)-porphyrin on an achiral poly(2-(dimethylamino)ethyl methylacrylate)-grafted ethylene-vinyl alcohol membrane
    Zhao, Lizhi
    Liu, Manman
    Li, Sensen
    Li, Ang
    An, Huiqin
    Ye, Hui
    Zhang, Yuzhong
    [J]. JOURNAL OF MATERIALS CHEMISTRY C, 2015, 3 (15) : 3650 - 3658
12345