Unique photoreactivity of mercury(II) 5,10,15,20-tetrakis (4-sulfonatophenyl)porphyrin

被引：28
|
作者：
Horváth, O
Valicsek, Z
Vogler, A
机构：
[1] Univ Veszprem, Dept Gen & Inorgan Chem, H-8201 Veszprem, Hungary
[2] Univ Regensburg, Inst Anorgan Chem, D-93040 Regensburg, Germany
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2004年 / 7卷 / 07期
基金：
匈牙利科学研究基金会;
关键词：
photophysics; photochemistry; charge transfer; dissociation; metalloporphyrin; mercury;
D O I：
10.1016/j.inoche.2004.05.004
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Deviating from coplanar metalloporphyrins, the photochemistry of the kinetically labile, sitting-atop mercury(II) 5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrin complex is characterized by irreversible porphyrin ligand to metal charge transfer and reversible dissociation. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码：854 / 857
页数：4
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