Electrochemical synthesis and a redetermination of Ni(acac)2(H2O)2 • H2O

被引：6

作者：

Zhou, XF ^{[1
]}

Han, AJ

Chu, DB

Huang, ZX

机构：

[1] Anhui Normal Univ, Inst Organ Chem, Wuhu 241000, Peoples R China

[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2001年 / 57卷

关键词：

D O I：

10.1107/S1600536801016208

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title complex, bis(acetylacetonato)diaquanickel(II) monohydrate, [Ni(C5H7O2)(2)(H2O)2)].H2O, was easily synthesized in high yield by electrochemical dissolution of nickel metal in an acetylacetone and ethanol solution via direct hydrolysis of the electrolyte solution at a temperature of 333 K. The crystal structure shows octahedral coordination of nickel with two trans aqua ligands. An uncoordinated water molecule engages in hydrogen bonding.

引用

页码：M506 / M508

页数：3

共 50 条

[31] H2O
黑夜
中国摄影, 2019, (07) : 54 - 57
[32] Theoretical studies of large water clusters: (H2O)(28), (H2O)(29), (H2O)(30), and (H2O)(31) hexakaidecahedral structures
Khan, A
JOURNAL OF CHEMICAL PHYSICS, 1997, 106 (13): : 5537 - 5540
[33] THE SIMPLE CLUSTERS (H3O+)(H2O)1, (H3O+)(H2O)2, (H3O+)(H2O)3
SCHAEFER, HF
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1985, 189 (APR-): : 103 - PHYS
[34] Theoretical studies of large water clusters: (H2O)28, (H2O)29, (H2O)30, and (H2O)31 hexakaidecahedral structures
J Chem Phys, 13 (5537):
[35] Deuterium exchange in the systems of H2O+/H2O and H3O+/H2O
Anicich, V. G.
Sen, A. D.
International Journal of Mass Spectrometry and Ion Processes, 172 (1-2):
[36] Deuterium exchange in the systems of H2O+/H2O and H3O+/H2O
Anicich, VG
Sen, AD
INTERNATIONAL JOURNAL OF MASS SPECTROMETRY, 1998, 172 (1-2) : 1 - 14
[37] Passivation of iron by oxidation in H2O and O2/H2O mixtures
Roosendaal, SJ
Bakker, JPR
Vredenberg, AM
Habraken, FHPM
SURFACE SCIENCE, 2001, 494 (03) : 197 - 205
[38] SORPTION ISOTHERMS AND SWELLING OF POPC IN H2O AND (H2O)-H-2
KLOSE, G
KONIG, B
PALTAUF, F
CHEMISTRY AND PHYSICS OF LIPIDS, 1992, 61 (03) : 265 - 270
[39] Ferromagnetism in malonato-bridged copper(II) complexes.: Synthesis, crystal structures, and magnetic properties of {[Cu(H2O)3][Cu(mal)2(H2O)]}n and {[Cu(H2O)4]2[Cu(mal)2(H2O)]}[Cu(mal)2(H2O)2]{[Cu(H2O)4][Cu(mal)2(H2O)2]} (H2mal = malonic acid)
Ruiz-Pérez, C
Sanchiz, J
Molina, MH
Lloret, F
Julve, M
INORGANIC CHEMISTRY, 2000, 39 (07) : 1363 - 1370
[40] H2 or H2O?
Valinotti, Diego
TCE, 2007, (789): : 58 - 58

← 1 2 3 4 5 →