A 1H NMR study on the electronic state of a chloride-bridged tetrakis(acetamidato)dirhodium complex

被引：0
|
作者：
Yamauchi, M
Takazaki, Y
Yang, ZY
Kawamura, T
Ikeda, R
机构：
[1] Univ Tsukuba, Dept Chem, Tsukuba, Ibaraki 3058571, Japan
[2] Gifu Univ, Fac Engn, Dept Chem, Gifu 5011193, Japan
来源：
CHEMISTRY LETTERS | 2004年 / 33卷 / 02期
关键词：
D O I：
10.1246/cl.2004.110
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A temperature dependence of H-1 NMR spin-lattice relaxation time in a zig-zag chain of chloride-bridged tetrakis(acetamidato)dirhodium was measured. The observed H-1 relaxation was well explained by the fluctuation of the magnetic dipolar interaction between proton and paramagnetic electron spins, where each unpaired spin is coupled by the one-dimensional antiferromagnetic interaction above 35 K. The slight change of the electronic state in the Rh dimer was observed below 35 K.
引用
收藏
页码：110 / 111
页数：2
相关论文
共 50 条
  • [41] Comparative study of the complex forming ability and enantioselectivity of cyclodextrin polymers by CE and 1H NMR
    Danel, Cecile
    Azaroual, Nathalie
    Chavaria, Cedric
    Odou, Pascal
    Martel, Bernard
    Vaccher, Claude
    CARBOHYDRATE POLYMERS, 2013, 92 (02) : 2282 - 2292
  • [42] ~1H NMR Investigation of Supramolecular Complex between β-Cyclodextrin and Cholesterol
    JIANG Huiming1
    2. College of Life Science
    Wuhan University Journal of Natural Sciences, 2011, 16 (01) : 79 - 82
  • [43] Metabolomic Study of Rheumatoid Arthritis Using 1H Nuclear Magnetic Resonance (1H NMR)
    Tsezou, Konstantina
    Benaki, Dimitra
    Iliou, Katerina
    Mikros, Emmanuel
    Vlachoyiannopoulos, Panayiotis
    ARTHRITIS & RHEUMATOLOGY, 2021, 73 : 43 - 46
  • [44] State of water in amorphous silica samples from rice hulls:: A 1H NMR study
    Zemnukhova, L. A.
    Babushkina, T. A.
    Klimova, T. P.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2007, 77 (06) : 1008 - 1013
  • [45] A 1H and 13C NMR and UV study of the state of hydroxyacetone in aqueous solutions
    Glushonok, GK
    Glushonok, TG
    Maslovskaya, LA
    Shadyro, OI
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2003, 73 (07) : 1027 - 1031
  • [46] State of water in amorphous silica samples from rice hulls: A 1H NMR study
    L. A. Zemnukhova
    T. A. Babushkina
    T. P. Klimova
    Russian Journal of General Chemistry, 2007, 77 : 1008 - 1013
  • [47] A 1H and 13C NMR and UV Study of the State of Hydroxyacetone in Aqueous Solutions
    G. K. Glushonok
    T. G. Glushonok
    L. A. Maslovskaya
    O. I. Shadyro
    Russian Journal of General Chemistry, 2003, 73 : 1027 - 1031
  • [48] Liquid state 1H high field NMR in food analysis
    Mannina, Luisa
    Sobolev, Anatoly P.
    Viel, Stephane
    PROGRESS IN NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY, 2012, 66 : 1 - 39
  • [49] Optically Enhanced Solid-State 1H NMR Spectroscopy
    De Biasi, Federico
    Hope, Michael A.
    Avalos, Claudia E.
    Karthikeyan, Ganesan
    Casano, Gilles
    Mishra, Aditya
    Badoni, Saumya
    Stevanato, Gabriele
    Kubicki, Dominik J.
    Milani, Jonas
    Ansermet, Jean-Philippe
    Rossini, Aaron J.
    Lelli, Moreno
    Ouari, Olivier
    Emsley, Lyndon
    Journal of the American Chemical Society, 2023,
  • [50] Optically Enhanced Solid-State 1H NMR Spectroscopy
    De Biasi, Federico
    Hope, Michael A.
    Avalos, Claudia E.
    Karthikeyan, Ganesan
    Casano, Gilles
    Mishra, Aditya
    Badoni, Saumya
    Stevanato, Gabriele
    Kubicki, Dominik J.
    Milani, Jonas
    Ansermet, Jean-Philippe
    Rossini, Aaron J.
    Lelli, Moreno
    Ouari, Olivier
    Emsley, Lyndon
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2023, 145 (27) : 14874 - 14883
12345