Waste Face Surgical Mask Transformation into Crude Oil and Nanostructured Electrocatalysts for Fuel Cells and Electrolyzers

被引:36
|
作者
Muhyuddin, Mohsin [1 ]
Filippi, Jonathan [2 ]
Zoia, Luca [3 ]
Bonizzoni, Simone [1 ]
Lorenzi, Roberto [1 ]
Berretti, Enrico [2 ]
Capozzoli, Laura [2 ]
Bellini, Marco [2 ]
Ferrara, Chiara [1 ]
Lavacchi, Alessandro [2 ]
Santoro, Carlo [1 ]
机构
[1] Univ Milano Bicocca, Dept Mat Sci, U5 Via Cozzi 55, I-20125 Milan, Italy
[2] CNR, Ist Chim Composti OrganoMetall ICCOM, Via Madonna Piano 10, I-50019 Florence, Italy
[3] Univ Milano Bicocca, Dept Earth & Environm Sci, Bldg U01,Piazza Sci 1, I-20126 Milan, Italy
关键词
crude oil; hydrogen evolution reaction; oxygen reduction reaction; surgical mask; valorization; OXYGEN REDUCTION REACTION; NITROGEN-CARBON CATALYSTS; HYDROGEN EVOLUTION; RAMAN-SPECTROSCOPY; TRANSITION-METAL; THERMAL-DEGRADATION; POWER-GENERATION; ALKALINE MEDIA; POLYPROPYLENE; PHTHALOCYANINE;
D O I
10.1002/cssc.202102351
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel route for the valorization of waste into valuable products was developed. Surgical masks commonly used for COVID 19 protection by stopping aerosol and droplets have been widely used, and their disposal is critical and often not properly pursued. This work intended to transform surgical masks into platinum group metal-free electrocatalysts for oxygen reduction reaction (ORR) and hydrogen evolution reaction (HER) as well as into crude oil. Surgical masks were subjected to controlled-temperature and -atmosphere pyrolysis, and the produced char was then converted into electrocatalysts by functionalizing it with metal phthalocyanine of interest. The electrocatalytic performance characterization towards ORR and HER was carried out highlighting promising activity. At different temperatures, condensable oil fractions were acquired and thoroughly analyzed. Transformation of waste surgical masks into electrocatalysts and crude oil can open new routes for the conversion of waste into valuable products within the core of the circular economy.
引用
收藏
页数:14
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