Waste Face Surgical Mask Transformation into Crude Oil and Nanostructured Electrocatalysts for Fuel Cells and Electrolyzers

被引:36
|
作者
Muhyuddin, Mohsin [1 ]
Filippi, Jonathan [2 ]
Zoia, Luca [3 ]
Bonizzoni, Simone [1 ]
Lorenzi, Roberto [1 ]
Berretti, Enrico [2 ]
Capozzoli, Laura [2 ]
Bellini, Marco [2 ]
Ferrara, Chiara [1 ]
Lavacchi, Alessandro [2 ]
Santoro, Carlo [1 ]
机构
[1] Univ Milano Bicocca, Dept Mat Sci, U5 Via Cozzi 55, I-20125 Milan, Italy
[2] CNR, Ist Chim Composti OrganoMetall ICCOM, Via Madonna Piano 10, I-50019 Florence, Italy
[3] Univ Milano Bicocca, Dept Earth & Environm Sci, Bldg U01,Piazza Sci 1, I-20126 Milan, Italy
关键词
crude oil; hydrogen evolution reaction; oxygen reduction reaction; surgical mask; valorization; OXYGEN REDUCTION REACTION; NITROGEN-CARBON CATALYSTS; HYDROGEN EVOLUTION; RAMAN-SPECTROSCOPY; TRANSITION-METAL; THERMAL-DEGRADATION; POWER-GENERATION; ALKALINE MEDIA; POLYPROPYLENE; PHTHALOCYANINE;
D O I
10.1002/cssc.202102351
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel route for the valorization of waste into valuable products was developed. Surgical masks commonly used for COVID 19 protection by stopping aerosol and droplets have been widely used, and their disposal is critical and often not properly pursued. This work intended to transform surgical masks into platinum group metal-free electrocatalysts for oxygen reduction reaction (ORR) and hydrogen evolution reaction (HER) as well as into crude oil. Surgical masks were subjected to controlled-temperature and -atmosphere pyrolysis, and the produced char was then converted into electrocatalysts by functionalizing it with metal phthalocyanine of interest. The electrocatalytic performance characterization towards ORR and HER was carried out highlighting promising activity. At different temperatures, condensable oil fractions were acquired and thoroughly analyzed. Transformation of waste surgical masks into electrocatalysts and crude oil can open new routes for the conversion of waste into valuable products within the core of the circular economy.
引用
收藏
页数:14
相关论文
共 50 条
  • [1] Nanostructured Electrocatalysts for Advanced Applications in Fuel Cells
    Omeiza, Lukman Ahmed
    Abdalla, Abdalla M.
    Wei, Bo
    Dhanasekaran, Anitha
    Subramanian, Yathavan
    Afroze, Shammya
    Reza, Md Sumon
    Abu Bakar, Saifullah
    Azad, Abul Kalam
    ENERGIES, 2023, 16 (04)
  • [2] Oxygen electrocatalysts for water electrolyzers and reversible fuel cells: status and perspective
    Park, Sehkyu
    Shao, Yuyan
    Liu, Jun
    Wang, Yong
    ENERGY & ENVIRONMENTAL SCIENCE, 2012, 5 (11) : 9331 - 9344
  • [3] Design of nanostructured electrocatalysts for direct methanol fuel cells
    Park, KW
    Sung, YE
    JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2006, 12 (02) : 165 - 174
  • [4] Recent progress in nanostructured electrocatalysts for PEM fuel cells
    Zhang, Sheng
    Shao, Yuyan
    Yin, Geping
    Lin, Yuehe
    JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (15) : 4631 - 4641
  • [5] Powering Fuel Cells with Crude Oil
    Wlodarczyk, Pawel
    Wlodarczyk, Barbara
    JOURNAL OF POWER TECHNOLOGIES, 2013, 93 (05): : 394 - 397
  • [6] Metalloporphyrins and related metallomacrocycles as electrocatalysts for use in polymer electrolyte fuel cells and water electrolyzers
    Yamazaki, Shin-ichi
    COORDINATION CHEMISTRY REVIEWS, 2018, 373 : 148 - 166
  • [7] Catalytic Transformation of Waste Polymers to Fuel Oil
    Keane, Mark A.
    CHEMSUSCHEM, 2009, 2 (03) : 207 - 214
  • [8] Nanostructured Anode Pt–Ru Electrocatalysts for Direct Methanol Fuel Cells
    Elise E. Switzer
    Abhaya K. Datye
    Plamen Atanassov
    Topics in Catalysis, 2007, 46 : 334 - 338
  • [9] RADIATION EFFECTS ON PLATINUM NANOSTRUCTURED ELECTROCATALYSTS FOR POLYMER ELECTROLYTE FUEL CELLS
    Cemmi, A.
    Paoletti, C.
    Pozio, A.
    Baccaro, S.
    Giorgi, L.
    Serra, E.
    ASTROPARTICLE, PARTICLE AND SPACE PHYSICS, DETECTORS AND MEDICAL PHYSICS APPLICATIONS, 2008, 4 : 540 - +
  • [10] Synthesis of Nanostructured PdMo Electrocatalysts for Oxygen Reduction Reaction in Fuel Cells
    Cao, Chongjiang
    Liu, Xiaogeng
    Liu, Qin
    CURRENT TRENDS IN THE DEVELOPMENT OF INDUSTRY, PTS 1 AND 2, 2013, 785-786 : 390 - 394