STRUCTURE OF bis(CITRATO) GERMANATES WITH DIFFERENT TYPES OF CATIONS: (Hphen)2[Ge(HCit)2•3H2O], [CuCl(phen)2]2[Ge(HCit)2••6H2O], WHERE H4Cit IS CITRIC ACID, phen IS 1,10-PHENANTHROLINE

被引：8
|
作者：
Seifullina, I. I. [1 ]
Martsinko, E. E. [1 ]
Chebanenko, E. A. [1 ]
Pirozhok, O. V. [1 ]
Dyakonenko, V. V. [2 ]
Shishkina, S. V. [2 ,3 ]
机构：
[1] Mechnikov Odessa Natl Univ, Odessa, Ukraine
[2] Natl Acad Sci, Inst Single Crystals, Sci & Technol Complex, Kharkov, Ukraine
[3] Kharkov Natl Univ, Kharkov, Ukraine
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2017年 / 58卷 / 03期
关键词：
germanium dioxide; citric acid; 1,10-phenanthroline; copper(II) chloride; coordination compounds; molecular structure; single crystal X-ray diffraction analysis; CENTER-DOT 5H(2)O; CRYSTAL-STRUCTURE; COMPLEXES; PENTAHYDRATE; LIGANDS; NITRATE;
D O I：
10.1134/S0022476617030143
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The procedures are developed and the complexation products are preparatively isolated from GeO2-H-4 Cit-phen- CH3CN-H2O (I) and GeO2-H(4)Cit-CuCl2-phen-C2H5OH-H2O (II) systems (phen is 1,10-phenanthroline, H(4)Cit is citric acid). The (Hphen)(2)[Ge(HCit)(2)] center dot 3H(2)O (I) and [Cu(phen)(2)Cl](2) [Ge(HCit)(2)]center dot center dot 6H(2)O (II) complexes are characterized by elemental analysis, IR spectroscopy, and single crystal X-ray diffraction. The compounds are formed from centrosymmetric octahedral [Ge(HCit)(2)](2-) anions, Hphen(+) (I) and [Cu(phen)(2)Cl](+) (II) cations, and crystallization water molecules. The structural units in the crystals are linked via a system of hydrogen bonds.
引用
收藏
页码：532 / 538
页数：7
相关论文
共 50 条
  • [21] Ammonium and potassium citratogermanates(IV): Synthesis, chemical compositions, and structures. The crystal structures of (NH4)[Ge(OH)(H2Cit)2] · H2O and K4[Ge(HCit)2(H2Cit)] · 3H2O
    E. E. Martsinko
    L. Kh. Minacheva
    E. A. Chebanenko
    A. B. Ilyukhin
    I. I. Seifullina
    V. S. Sergienko
    Russian Journal of Coordination Chemistry, 2013, 39 : 629 - 635
  • [22] [Co(phen) (thiourea) (H2O)Cl2]•thiourea (phen is 1,10-phenanthroline)
    Suescun, L
    Mariezcurrena, RA
    Mombrú, AW
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1999, 55 : 2065 - 2068
  • [23] [Co(phen)(thiourea)(H2O)Cl2]·thiourea (phen is 1,10-phenanthroline)
    Suescun, Leopoldo
    Mariezcurrena, Raul A.
    Mombru, Alvaro W.
    Acta Crystallographica, Section C: Crystal Structure Communications, 1999, 55 (12): : 2065 - 2068
  • [24] Induction of apoptotic cell death by 1,10-phenanthroline (phen), [Ag2(phen)3(mal)]•2H2O, [Cu(phen)2(mal)]•2H2O and [Mn(phen)2(mal)]•2H2O (malH2•malonic acid) using human cancer cells
    Deegan, C.
    McCann, M.
    Devereux, M.
    Coyle, B.
    Egan, D. A.
    ANTICANCER RESEARCH, 2007, 27 (3A) : 1380 - 1380
  • [25] Syntheses and crystal structures of [M2(H2O)2(phen)2(C7H10O4)2]•4H2O with M = MnII, CuII and phen=1,10-phenanthroline
    Zheng, YQ
    Lin, JL
    Sun, J
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2001, 627 (08): : 1997 - 2001
  • [26] Sebacato-bridged Cu(II) phen complexes:: syntheses and crystal structures of 2∞[Cu2(phen)2L4/2](H2O)6 and [(phen)2Cu(μ-L)Cu(phen)2](HL)2(H2L)(H2O)4 (H2L = sebacic acid; phen = 1,10-phenanthroline)
    Wei, DY
    Kong, ZP
    Zheng, YQ
    POLYHEDRON, 2002, 21 (16) : 1621 - 1628
  • [27] In vitro cancer chemotherapeutic activity of 1,10-phenanthroline (phen), [Ag2(phen)3(mal)] • 2H2O, [Cu(phen)2(mal)] • 2H2O and [Mn(phen)2(mal)] 2H2O (malH2=malonic acid) using human cancer cells
    Deegan, Carol
    McCann, Malachy
    Devereux, Michael
    Coyle, Barry
    Egan, Denise A.
    CANCER LETTERS, 2007, 247 (02) : 224 - 233
  • [28] Synthesis and crystal structure of a novel dinuclear copper(II) complex, [Cu2(phen)2(H2O)2(OH)2](HCO3)2 •6 H2O with phen=1,10-phenanthroline
    Zheng, YQ
    Jie, S
    Lin, JL
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2000, 626 (03): : 613 - 615
  • [29] Crystal structure and absorption spectra of bis[(neptunium(V)dioxo)azidoaqua(1,10-phenanthroline)] trihydrate [NpO2(N3)(Phen)(H2O)]2 • 3H2O
    Budantseva, NA
    Andreev, GB
    Fedoseev, AM
    Antipin, MY
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2003, 29 (04) : 265 - 270
  • [30] Crystal Structure and Absorption Spectra of Bis[(neptunium(V)dioxo)azidoaqua(1,10-phenanthroline)] Trihydrate [NpO2(N3)(Phen)(H2O)]2 · 3H2O
    N. A. Budantseva
    G. B. Andreev
    A. M. Fedoseev
    M. Yu. Antipin
    Russian Journal of Coordination Chemistry, 2003, 29 : 265 - 270
12345