The effect of solvent addition on fructose dehydration to 5-hydroxymethylfurfural in biphasic system over zeolites

被引：180
|
作者：
Ordomsky, V. V. [1 ]
van der Schaaf, J. [1 ]
Schouten, J. C. [1 ]
Nijhuis, T. A. [1 ]
机构：
[1] Eindhoven Univ Technol, Lab Chem Reactor Engn, NL-5600 MB Eindhoven, Netherlands
来源：
JOURNAL OF CATALYSIS | 2012年 / 287卷
关键词：
Fructose dehydration; HMF; Organic solvent addition; Zeolites; Silylation; Solvent addition; SURFACE MODIFICATION; ACID CATALYST; CONVERSION; 5-HYDROXYMETHYL-2-FURALDEHYDE; BIOMASS; TRANSFORMATION; DERIVATIVES; PHOSPHATE; CHEMICALS; GLUCOSE;
D O I：
10.1016/j.jcat.2011.12.002
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The effect of organic solvent addition during dehydration of fructose over zeolites has been investigated as a way to enhance the 5-hydroxymethylfurfural (HMF) selectivity. The catalysts were characterized by chemical analysis, XRD, nitrogen adsorption-desorption and TPD NH3. The selectivity of HMF formation during the addition of methyl isobutyl ketone (MIBK) is significantly increased, but its effect decreases in the order: MOR > ZSM-5 > BEA > amorphous aluminosilicate, which corresponds to the order of the decrease in the strength of the acid sites. An initial increase in the selectivity to HMF over zeolites after addition of organic solvent is attributed to the suppression of humins formation due to filling of the pores of zeolite with MIBK. Testing of silylated samples with deactivated surface acid sites indicates that in a biphasic system, the increase in the selectivity at higher conversions is induced by suppression by the solvent of the activity of external acid sites responsible for the unselective transformation of fructose. (C) 2011 Elsevier Inc. All rights reserved.
引用
收藏
页码：68 / 75
页数：8
相关论文
共 50 条
  • [21] Conversion of fructose into furfural or 5-hydroxymethylfurfural over HY zeolites selectively in γ-butyrolactone
    Wang, Liqin
    Guo, Heqin
    Xie, Qilong
    Wang, Jungang
    Hou, Bo
    Jia, Litao
    Cui, Jinglei
    Li, Debao
    APPLIED CATALYSIS A-GENERAL, 2019, 572 : 51 - 60
  • [22] Catalytic dehydration of fructose to 5-hydroxymethylfurfural over a mesoscopically assembled sulfated zirconia nanoparticle catalyst in organic solvent
    Wang, Ningning
    Yao, Yuan
    Li, Wei
    Yang, Yan
    Song, Zhanxin
    Liu, Wentao
    Wang, Haijun
    Xia, Xiao-Feng
    Gao, Haiyan
    RSC ADVANCES, 2014, 4 (100): : 57164 - 57172
  • [23] Dehydration of fructose into 5-hydroxymethylfurfural in the presence of ionic liquids
    Lansalot-Matras, C
    Moreau, C
    CATALYSIS COMMUNICATIONS, 2003, 4 (10) : 517 - 520
  • [24] Catalytic dehydration of fructose into 5-hydroxymethylfurfural over HBeta zeolite in [EMIM]Br
    Liu, Min
    Jia, Songyan
    Wan, Yi
    Zuo, Yi
    Guo, Xinwen
    Song, Chunshan
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2009, 238
  • [25] Dehydration of Fructose to 5-Hydroxymethylfurfural Catalyzed by Modified Mordenite
    Ma, Zhongmin
    Li, Gang
    Lü, Qiang
    Shiyou Xuebao, Shiyou Jiagong/Acta Petrolei Sinica (Petroleum Processing Section), 2024, 40 (03): : 650 - 659
  • [26] Production and purification of 5-hydroxymethylfurfural from fructose dehydration
    Liu Y.-X.
    Li Y.
    Fang X.
    Yao E.
    Wei Z.-J.
    Gao Xiao Hua Xue Gong Cheng Xue Bao/Journal of Chemical Engineering of Chinese Universities, 2022, 36 (02): : 211 - 217
  • [27] Selective fructose dehydration to 5-hydroxymethylfurfural from a fructose-glucose mixture over a sulfuric acid catalyst in a biphasic system: Experimental study and kinetic modelling
    Guo, Wenze
    Zhang, Zheng
    Hacking, Jasper
    Heeres, Hero Jan
    Yue, Jun
    CHEMICAL ENGINEERING JOURNAL, 2021, 409
  • [28] The Effect of Imidazolium Ionic Liquid on the Dehydration of Fructose to 5-Hydroxymethylfurfural, and a Room Temperature Catalytic System
    Lai, Linke
    Zhang, Yugen
    CHEMSUSCHEM, 2010, 3 (11) : 1257 - 1259
  • [29] Preparation of 5-hydroxymethylfurfural from fructose and precursors over H-form zeolites
    Moreau, Claude
    Durand, Robert
    Pourcheron, Cecile
    Razigade, Sylvie
    INDUSTRIAL CROPS AND PRODUCTS, 1994, 3 (1-2) : 85 - 90
  • [30] Alcohol Effect and the Related Mechanism on Fructose Dehydration into 5-Hydroxymethylfurfural in the Deep Eutectic Solvent of [Emim]Cl/Alcohol
    Zhang, Jing
    Xiao, Yuyan
    Zhong, Yaohua
    Du, Na
    Huang, Xirong
    ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2016, 4 (07): : 3995 - 4002
12345