Titanyl acetylacetonate as an efficient catalyst for a mild and convenient reduction of carbonyl compounds with NaBH4 under aprotic condition

被引：8
|
作者：
Zeynizadeh, B [1 ]
机构：
[1] Urmia Univ, Fac Sci, Dept Chem, Orumiyeh 57159165, Iran
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2003年 / 58卷 / 12期
关键词：
titanyl acetylacetonate; carbonyl compounds; borohydride reduction;
D O I：
10.1515/znb-2003-1211
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Titanyl acetylacetonate, TiO(acac)(2), is used as an efficient catalyst for the reduction of carbonyl compounds with sodium borohydride under aprotic condition. Reduction reactions are performed in CH3CN and THE The corresponding alcohols are obtained in high to excellent yields and the chemoselective reduction of aldehydes over ketones is achieved successfully.
引用
收藏
页码：1220 / 1226
页数：7
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