Phase behavior of triblock copolymers varying in molecular asymmetry

被引：50

作者：

Hamersky, MW ^{[1
]}

Smith, SD

Gozen, AO

Spontak, RJ

机构：

[1] Procter & Gamble Co, Miami Valley Innovat Ctr, Cincinnati, OH 45061 USA

[2] N Carolina State Univ, Dept Chem & Biomol Engn, Raleigh, NC 27695 USA

[3] N Carolina State Univ, Dept Mat Sci & Engn, Raleigh, NC 27695 USA

来源：

PHYSICAL REVIEW LETTERS | 2005年 / 95卷 / 16期

关键词：

D O I：

10.1103/PhysRevLett.95.168306

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

The transformation from A(1)B diblock copolymer to A(1)BA(2) triblock copolymers varying in molecular asymmetry is investigated as the A(2) end block is progressively grown via chemical synthesis. Dynamic rheological measurements show that the order-disorder transition (ODT) temperatures of two copolymer series differing in composition and molecular weight decrease when the A(2) block is short relative to the A(1) block, and then increase as the length of the A(2) block is increased further. The resultant ODT minimum, predicted by mean-field theory, is attributed to mixing between long B and short A(2) blocks.

引用

页数：4

共 50 条

[41] Comprehensive phase behavior of poly(isoprene-b-styrene-b-ethylene oxide) triblock copolymers
Chatterjee, Joon
Jain, Sumeet
Bates, Frank S.
MACROMOLECULES, 2007, 40 (08) : 2882 - 2896
[42] Effect of solvophobicity on the phase behavior of linear ABC triblock copolymers in selective solvents: a Monte Carlo study
Gao, Zhihua
Cui, Jie
Han, Yuanyuan
Jiang, Wei
RSC ADVANCES, 2018, 8 (47): : 26959 - 26967
[43] A molecular dynamics simulation on the self-assembly of ABC triblock copolymers, 1 - Effects of block composition in symmetric triblock copolymers
Ko, MJ
Kim, SH
Jo, WH
MACROMOLECULAR THEORY AND SIMULATIONS, 2001, 10 (04) : 381 - 388
[44] Theoretical study on the phase behavior of amphiphilic triblock copolymers PEO-PPO-PEO in aqueous solutions
Jiang Run
Jin Qing-Hua
Li Bao-Hui
Ding Da-Tong
Shi An-Chang
ACTA CHIMICA SINICA, 2007, 65 (09) : 860 - 866
[45] Dynamics of solutions of triblock copolymers in a selective solvent: Effect of varying copolymer concentration
Konak, C
Fleischer, G
Tuzar, Z
Bansil, R
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2000, 38 (10) : 1312 - 1322
[46] Theory of phase behavior of poly(oxyethylene)-poly(oxypropylene)-poly(oxyethylene) triblock copolymers in aqueous solutions
Noolandi, J
Shi, AC
Linse, P
MACROMOLECULES, 1996, 29 (18) : 5907 - 5919
[47] Phase behavior of triblock copolymers upon incorporation of non-parent, midblock-associating additives
Laurer, JH
Mulling, JF
Bukovnik, R
Spontak, RJ
MORPHOLOGICAL CONTROL IN MULTIPHASE POLYMER MIXTURES, 1997, 461 : 69 - 74
[48] Influence of the block sequence on the morphological behavior of ABC triblock copolymers
Abetz, V., 2000, Elsevier Science Ltd, Exeter (41)
[49] Influence of the block sequence on the morphological behavior of ABC triblock copolymers
Hückstädt, H
Göpfert, A
Abetz, V
POLYMER, 2000, 41 (26) : 9089 - 9094
[50] Ionic Liquids Mediated Micellization of Pluronic Copolymers: Aggregation Behavior of Amphiphilic Triblock Copolymers
Kumar, Krishan
Umapathi, Reddicherla
Venkatesu, Pannuru
JOURNAL OF PHYSICAL CHEMISTRY B, 2023, 127 (10): : 2107 - 2120

← 1 2 3 4 5 →