A ring-opening cross-metathesis reaction of N-trialkylsilyl 2-azabicyclo[2.2.1]hept-5-en-3-one with allyltrimethylsilane

被引：7
|
作者：
Ishikura, M [1 ]
Hasunuma, M
Yanada, K
机构：
[1] Hlth Sci Univ Hokkaido, Fac Pharmaceut Sci, Ishikari, Hokkaido 0610293, Japan
[2] Setsunan Univ, Fac Pharmaceut Sci, Hirakata, Osaka 5730101, Japan
来源：
HETEROCYCLES | 2005年 / 65卷 / 11期
关键词：
D O I：
10.3987/COM-05-10533
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Subjection of N-trialkylsilyl-2-azabicyclo[2.2.1] hept-5-en-3-one (1) to a ring-opening cross-metathesis reaction with allyltrimethylsilane in the presence of Grubbs' catalyst was found to allow the predominate formation of pyrrolidine (3) over pyrrolidine (4).
引用
收藏
页码：2587 / 2592
页数：6
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