A ring-opening cross-metathesis reaction of N-trialkylsilyl 2-azabicyclo[2.2.1]hept-5-en-3-one with allyltrimethylsilane

被引：7

作者：

Ishikura, M ^{[1
]}

Hasunuma, M

Yanada, K

机构：

[1] Hlth Sci Univ Hokkaido, Fac Pharmaceut Sci, Ishikari, Hokkaido 0610293, Japan

[2] Setsunan Univ, Fac Pharmaceut Sci, Hirakata, Osaka 5730101, Japan

来源：

HETEROCYCLES | 2005年 / 65卷 / 11期

关键词：

D O I：

10.3987/COM-05-10533

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Subjection of N-trialkylsilyl-2-azabicyclo[2.2.1] hept-5-en-3-one (1) to a ring-opening cross-metathesis reaction with allyltrimethylsilane in the presence of Grubbs' catalyst was found to allow the predominate formation of pyrrolidine (3) over pyrrolidine (4).

引用

页码：2587 / 2592

页数：6

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