Chiral anisotropic reagents for determining the absolute configuration of secondary alcohols and carboxylic acids

被引：13

作者：

Kusumi, T ^{[1
]}

Yabuuchi, T

Takahashi, H

Ooi, T

机构：

[1] Univ Tokushima, Fac Pharmaceut Sci, Tokushima 7708505, Japan

[2] Taisho Pharmaceut Co Ltd, Res Ctr, Kita Ku, Yoshino, Saitama 3319530, Japan

[3] Tokyo Univ Pharm & Life Sci, Dept Life Sci, Hachioji, Tokyo 1920392, Japan

来源：

JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN | 2005年 / 63卷 / 11期

关键词：

D O I：

10.5059/yukigoseikyokaishi.63.1102

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Based on the modified Mosher's method, we have developed several chiral anisotropic reagents. Together with a unique application of the modified Mosher's method to an enantiomeric mixture, utility of methoxy-(1- and 2-naphthyl)acetic acids (1NMA, 2NMA and other analogues) and phenylglycine methyl ester (PGME) in elucidation of the absolute configuration of secondary alcohols, amines, and carboxylic is summarized.

引用

页码：1102 / 1114

页数：13

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