Effects of surfactants on mechanical and thermal properties of soy-based polyurethane foams

被引:15
|
作者
Dhaliwal, Gurjot S. [1 ]
Anandan, Sudharshan [1 ]
Bose, Mousumi [2 ]
Chandrashekhara, K. [1 ]
Nam, Paul [2 ]
机构
[1] Missouri Univ Sci & Technol, Dept Mech & Aerosp Engn, Rolla, MO 65409 USA
[2] Missouri Univ Sci & Technol, Dept Chem, Rolla, MO 65409 USA
关键词
Cell density; environmentally friendly blowing agent; polyurethane foams; structural foams; surface tension; surfactant; OIL-BASED POLYOL; POLYETHER POLYOL; FUNCTIONALITY;
D O I
10.1177/0021955X20912200
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Polyurethane foams are widely used for insulation applications due to their high insulation properties as compared to conventional materials such as extruded polystyrene foam and mineral wool. In this study, soy-based polyurethane foams were prepared using five different surfactants while keeping other components such as soy-based polyol, diisocyanate, catalyst, and blowing agent (water) constant. Prepared samples were tested for mechanical and thermal properties to evaluate the effect of different surfactants used in varying quantities. The morphology of the foam samples was observed using a scanning electron microscope. Seventeen fold reduction in the cell size was observed with an increase in the amount of surfactant from 0.5 to 5.0 g. Samples with higher amounts of surfactant also exhibited a higher number of closed cells. Better thermal insulation was observed for samples with 2.0 and 5.0 g of surfactant as compared to samples with 0.5 g of surfactant. A similar trend was observed in the mechanical strength, moisture absorbance, and density of the fabricated foam samples.
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页码:611 / 629
页数:19
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