Selective N-Alkylation of Aromatic Primary Amines Catalyzed by Bio-catalyst or Deep Eutectic Solvent

被引：154
|
作者：
Singh, Balvant [1 ]
Lobo, Hyacintha [1 ]
Shankarling, Ganapati [1 ]
机构：
[1] Dyestuff Technol, Inst Chem Technol, Bombay 400019, Maharashtra, India
来源：
CATALYSIS LETTERS | 2011年 / 141卷 / 01期
关键词：
N-alkylation; Aromatic primary amines; Deep eutectic solvent; Lipase; ESTERS;
D O I：
10.1007/s10562-010-0479-9
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Biocatalysts or deep eutectic solvents (DES) are effective for selective N-alkylation of various aromatic primary amines. These methods avoided complexity of multiple alkylations giving products in good yields. Both DES and lipase can be recycled and re-used at least five times. In addition, these catalysts are biodegradable, non-toxic and cost-effective.
引用
收藏
页码：178 / 182
页数：5
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