Asymmetric synthesis XXVIII: Novel chiral aminophosphine phosphinite ligand and its application in homogeneous catalytic asymmetric hydrogenation of dehydroamino acid derivatives

被引：0
|
作者：
Mi, AQ [1 ]
Lou, RG
Jiang, YZ
Deng, JG
Qin, Y
Fu, FM
Hu, WH
Chan, ASC
机构：
[1] Chinese Acad Sci, Chengdu Inst Organ Chem, Union Lab Asymmetr Synth, Chengdu 610041, Peoples R China
[2] Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Hong Kong, Hong Kong
来源：
SYNLETT | 1998年 / 08期
关键词：
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Novel chiral aminophosphine phosphinite, DPAMPP was designed and synthesized from (1S,2R)-1,2-diphenyl-2-aminoethanol. Its cationic rhodium complex has been found to be an excellent catalyst for enantioselective hydrogenation of dehydroamino acids (more than 95.0%e.e.).
引用
收藏
页码：847 / +
页数：3
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