Aerobic oxidation of benzyl alcohol over TEMPO-functionalized polyimide as a heterogeneous catalyst

被引：10

作者：

Nabae, Yuta ^{[1
]}

Mikuni, Masatomo ^{[1
]}

Takusari, Nobuhiro ^{[1
]}

Hayakawa, Teruaki ^{[1
]}

Kakimoto, Masa-aki ^{[1
]}

机构：

[1] Tokyo Inst Technol, Tokyo, Japan

来源：

HIGH PERFORMANCE POLYMERS | 2017年 / 29卷 / 06期

关键词：

Hyperbranched polyimide; TEMPO; aerobic oxidation; heterogeneous catalyst; recyclable; HYPERBRANCHED AROMATIC POLYIMIDES; EFFICIENT;

D O I：

10.1177/0954008317696565

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Hyperbranched polyimide functionalized with 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) was studied as a heterogeneous catalyst for the aerobic oxidation of benzyl alcohol. The catalyst material was synthesized by an A(2) + B-3 polymerization of pyromellitic dianhydride and 1,3,5-tris(4-aminophenyl)benzene followed by an end-capping reaction with 4-amino-TEMPO. Selective aerobic oxidation of benzyl alcohol to benzaldehyde has been demonstrated using the prepared materials as a catalyst. The recyclability of these materials has been confirmed by recycling tests using the catalyst collected by filtration.

引用

下载

页码：646 / 650

页数：5

共 50 条

[41] Liquid phase catalytic oxidation of benzyl alcohol to benzaldehyde over vanadium phosphate catalyst
Behera, Gobinda Chandra
Parida, K. M.
APPLIED CATALYSIS A-GENERAL, 2012, 413 : 245 - 253
[42] Statistical Modelling and Analysis of the Aerobic Oxidation of Benzyl Alcohol over K–Mn/C Catalysts
Qinghu Tang
Yuanting Chen
Caixia Jasmine Zhou
Tao Chen
Yanhui Yang
Catalysis Letters, 2009, 128 : 210 - 220
[43] Highly active and selective thallium doped ceria supported gold catalyst for benzyl alcohol aerobic oxidation
Santra, Chiranjit
Bravo-Suarez, Juan
Tao, Franklin
Sreedhar, Bojja
Pandei, Jai
Chowdhury, Biswajit
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 252
[44] Kinetics of heterogeneous oxidation of benzyl alcohol with hydrogen peroxide
Chaudhari, MP
Sawant, SB
CHEMICAL ENGINEERING JOURNAL, 2005, 106 (02) : 111 - 118
[45] Kinetics of heterogeneous oxidation of benzyl alcohol with hydrogen peroxide
Chaudhari, Manisha P.
Sawant, Sudhirprakash B.
Chemical Engineering Journal, 1600, 106 (02): : 111 - 118
[46] Holey Lamellar High-Entropy Oxide as an Ultra-High-Activity Heterogeneous Catalyst for Solvent-free Aerobic Oxidation of Benzyl Alcohol
Feng, Danyang
Dong, Yangbo
Zhang, Liangliang
Ge, Xin
Zhang, Wei
Dai, Sheng
Qiao, Zhen-An
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 59 (44) : 19503 - 19509
[47] Creation of a monomeric Ru species on the surface of hydroxyapatite as an efficient heterogeneous catalyst for aerobic alcohol oxidation
Yamaguchi, K
Mori, K
Mizugaki, T
Ebitani, K
Kaneda, K
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (29) : 7144 - 7145
[48] Acid functionalized carbons as catalyst for glycerol etherification with benzyl alcohol
Chiosso, Maria E.
Lick, Ileana D.
Casella, Monica L.
Merlo, Andrea B.
BRAZILIAN JOURNAL OF CHEMICAL ENGINEERING, 2020, 37 (01) : 129 - 137
[49] Holey Lamellar High-Entropy Oxide as an Ultra-High-Activity Heterogeneous Catalyst for Solvent-free Aerobic Oxidation of Benzyl Alcohol
Feng, Danyang
Dong, Yangbo
Zhang, Liangliang
Ge, Xin
Zhang, Wei
Dai, Sheng
Qiao, Zhen-An
Advanced Materials, 2020, 132 (44) : 19671 - 19677
[50] Acid functionalized carbons as catalyst for glycerol etherification with benzyl alcohol
María E. Chiosso
Ileana D. Lick
Mónica L. Casella
Andrea B. Merlo
Brazilian Journal of Chemical Engineering, 2020, 37 : 129 - 137

← 1 2 3 4 5 →