Aerobic oxidation of benzyl alcohol over TEMPO-functionalized polyimide as a heterogeneous catalyst

被引：10

作者：

Nabae, Yuta ^{[1
]}

Mikuni, Masatomo ^{[1
]}

Takusari, Nobuhiro ^{[1
]}

Hayakawa, Teruaki ^{[1
]}

Kakimoto, Masa-aki ^{[1
]}

机构：

[1] Tokyo Inst Technol, Tokyo, Japan

来源：

HIGH PERFORMANCE POLYMERS | 2017年 / 29卷 / 06期

关键词：

Hyperbranched polyimide; TEMPO; aerobic oxidation; heterogeneous catalyst; recyclable; HYPERBRANCHED AROMATIC POLYIMIDES; EFFICIENT;

D O I：

10.1177/0954008317696565

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Hyperbranched polyimide functionalized with 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) was studied as a heterogeneous catalyst for the aerobic oxidation of benzyl alcohol. The catalyst material was synthesized by an A(2) + B-3 polymerization of pyromellitic dianhydride and 1,3,5-tris(4-aminophenyl)benzene followed by an end-capping reaction with 4-amino-TEMPO. Selective aerobic oxidation of benzyl alcohol to benzaldehyde has been demonstrated using the prepared materials as a catalyst. The recyclability of these materials has been confirmed by recycling tests using the catalyst collected by filtration.

引用

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页码：646 / 650

页数：5

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