Lithiation studies of [PhP(CH2Ph)3]Cl;: X-ray crystal structure of the phosphoniodiylide [(TMEDA)Li(PhCH)2PPh(CH2Ph)] and its rhodium and chromium complexes

被引：10

作者：

Bailey, PJ ^{[1
]}

Barrett, T ^{[1
]}

Parsons, S ^{[1
]}

机构：

[1] Univ Edinburgh, Dept Chem, Edinburgh EH9 3JJ, Midlothian, Scotland

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2001年 / 625卷 / 02期

基金：

英国工程与自然科学研究理事会;

关键词：

lithiation; X-ray crystal structures; phosphoniodiylide; pentamethylcyclopentadienyl;

D O I：

10.1016/S0022-328X(01)00674-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of the phosphonium salt [PhP(CH2Ph)(3)]Cl with three molar equivalents of (BuLi)-Bu-n gives the dilithiated species [Li2PhP(CHPh)(3)]. The crystal structure of the monolithiated species as its TMEDA adduct has been determined. Treatment of the dilithiate species with [((eta -C5Me5)MX2](2) (M = Cr, X = Br; M = Rh, X = Cl) provides [(eta -C5Me5)M{eta (2)-PhP(CH2Ph)(CHPh)(2)}X] containing chelating phosphoniodiylide ligands which are thought to be the hydrolysis products of the target complexes [{PhP(CHPh)(3)M(C5Me5)]. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：236 / 244

页数：9

共 50 条

[21] ALLOGONS - ISOMERISM IN CRYSTAL AND MOLECULAR STRUCTURE OF GREEN FORM OF DIBROMOBIS(BENZYLDIPHENYLPHOSPHINE)NICKEL(II) - NI P(CH2PH)PH2!2BR2 SQUARE!, 2NI P(CH2PH)PH2!2BR2 TETRAHEDRAL!
KILBOURN, BT
POWELL, HM
JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1970, (10): : 1688 - &
[22] Zirconium Complexes [Ph3PR]2+[ZrCl6]2–, R = Et, CH2Ph, CH2C(O)OMe: Synthesis and Structure
V. V. Sharutin
O. K. Sharutina
E. V. Lobanova
Russian Journal of Inorganic Chemistry, 2018, 63 : 1558 - 1563
[23] CARBON-CARBON BOND FORMATION IN (ETA-C5ME5)RU(NO)(CH2CL)R COMPLEXES (R = CH3, CH2OCH3, PH, CH2PH)
HUBBARD, JL
BURNS, RM
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1992, 203 : 417 - INOR
[24] Synthesis and reactivity of new silyl substituted monocyclopentadienyl zirconium complexes. X-ray molecular structure of [Zr{eta5-C5H4(SiMe2CH2Ph)}( CH2Ph) 3]
Ciruelo, G.
Cuenca, T.
Gomez, R.
Gomez-Sal, P.
Journal of Organometallic Chemistry, 547 (02):
[25] PREPARATION AND X-RAY STRUCTURE OF [RECL(PH2PCH2CH2PPH2)2]
HUGHES, DL
POMBEIRO, AJL
PICKETT, CJ
RICHARDS, RL
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 248 (03) : C26 - C28
[26] STERICALLY HINDERED ORGANOTIN COMPOUNDS .1. SYNTHESIS AND REACTION CHEMISTRY OF TRIS(TRIMETHYLSILYL)METHYLTIN(IV) DERIVATIVES - X-RAY CRYSTAL-STRUCTURES OF SN(CH2PH)2[C(SIME3)3](OSIME3) AND SN(CH2PH)2[C(SIME3)3]-[CH2CH=C(SIME3)2]
BROWN, P
MAHON, MF
MOLLOY, KC
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (09): : 2643 - 2651
[27] Crystal Packing Studies on C5(CH2Ph)5M (M=Mo,W) Derivatives. Conformational Behaviour of the C5(CH2Ph)5 Moiety.
Teresa Duarte, M.
Martins, Ana M.
Branquinho, Rita
Cui, Jinlan
Fernandes, Jose
Rodrigues, Sandra S.
Dias, Alberto R.
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2004, 60 : S302 - S302
[28] NMR spectroscopic study of the adduct formation and reactivity of homoleptic rare earth amides with alkali metal benzyl compounds, and the crystal structures of [Li(TMEDA)2][Nd{N(SiMe3)2}3(CH2Ph)] and [{Li(TMP)}2{Li(Ph)}]2
Rachor, Simon G.
Cleaves, Peter A.
Robertson, Stuart D.
Mansell, Stephen M.
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2018, 857 : 101 - 109
[29] Synthesis and Crystal Structure of 〔P（CH2Ph）Ph3〕〔PdWS4（S2CNC4H8）〕
LONG De-Liang
YAN Duan-Chao
CHENG Wen-Dan
HUANG Jin-Shun(State Key Laboratory of Structural Chemistry
结构化学, 1998, (02) : 155 - 158
[30] NEW ORGANOMETALLIC DIALKYLAMIDO COMPLEXES - X-RAY CRYSTAL-STRUCTURE OF PH2VN(CH2CH2NET2)2
WILLS, AR
EDWARDS, PG
HARMAN, M
HURSTHOUSE, MB
POLYHEDRON, 1989, 8 (11) : 1457 - 1459

← 1 2 3 4 5 →