Reactivity of Vinyl Ethers and Vinyl Ribosides in UV-Initiated Free Radical Copolymerization with Acceptor Monomers

被引：18
|
作者：
Pichavant, Loic [1 ]
Guillermain, Celine [1 ]
Coqueret, Xavier [1 ]
机构：
[1] Univ Reims, CNRS, UMR 6229, Inst Chim Mol Reims, F-51687 Reims 2, France
来源：
BIOMACROMOLECULES | 2010年 / 11卷 / 09期
关键词：
ALTERNATING COPOLYMERIZATION; STEREOCHEMICAL EVIDENCE; POLYMERIZATION; SECONDARY; POLYMERS; ALLYL; PHOTOPOLYMERIZATION; PARTICIPATION; FUNCTIONALITY; DEPROTECTION;
D O I：
10.1021/bm1005883
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
The reactivity of various vinyl ethers and vinyloxy derivatives of ribose in the presence of diethyl fumarate or diethyl maleate was investigated for evaluating the potential of donor-acceptor-type copolymerization applied to unsaturated monomers derived from renewable feedstock. The photochemically induced polymerization of model monomer blends in the bulk state was monitored by infrared spectroscopy. The method allowed us to examine the influence of monomer pair structure on the kinetic profiles. The simultaneous consumption of both monomers was observed, supporting an alternating copolymerization mechanism. A lower reactivity of the blends containing maleates compared with fumarates was confirmed. The obtained kinetic data revealed a general correlation between the initial polymerization rate and the Hansen parameter OH associated with the H-bonding aptitude of the donor monomer.
引用
收藏
页码：2415 / 2421
页数：7
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