Distribution of methyl red on the water-organic liquid interface in a microchannel

被引:35
|
作者
Surmeian, M [1 ]
Hibara, A
Slyadnev, M
Uchiyama, K
Hisamoto, H
Kitamori, T
机构
[1] Univ Tokyo, Sch Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1138656, Japan
[2] Kanagawa Acad Sci & Technol, Integrated Chem Project, Kawasaki, Kanagawa 2130012, Japan
[3] Japan Sci & Technol Corp, Precursory Res Embryon Sci & Technol 21, Kawaguchi, Saitama 3320012, Japan
关键词
microchips; thermal lens microscopy; methyl red; interface; molecular transport;
D O I
10.1081/AL-100104916
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Molecular transport across a water-organic liquid interface formed parallel to the side wall of a microchannel on microchips has been studied using methyl red as model compound and cyclohexane and n-octanol as organic solvents. The molecular transport was monitored by thermal lens microscopy and the kinetics of the process was studied for different concentrations and flow velocities. The influence of physicochemical interactions between the model compound and organic solvents on liquid-liquid interface was demonstrated in the microspace and corresponding partition coefficients were calculated which confirmed the experimental results.
引用
收藏
页码:1421 / 1429
页数:9
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