Scaling Laws in Supramolecular Polymer Networks

被引：78
|
作者：
Xu, Donghua
Craig, Stephen L. [1 ]
机构：
[1] Duke Univ, Dept Chem, Durham, NC 27708 USA
来源：
MACROMOLECULES | 2011年 / 44卷 / 13期
关键词：
SHEAR-THICKENING BEHAVIOR; CROSS-LINKED NETWORKS; VISCOELASTIC PROPERTIES; ASSOCIATIVE POLYMERS; DYNAMICS; COORDINATION; VISCOSITY; CHAINS;
D O I：
10.1021/ma200096s
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The linear rheological properties of networks formed by adding bis-Pd(II) cross-linkers to poly(4-vinylpyridine) (PVP) solution are examined, and the scaling law relationships between the zero shear viscosity (eta(0)) of the networks versus the concentration of PVP solution (C(PVP)), the concentration of cross-linkers (C(X)), and the number density of elastically active chains (v(phantom)) are experimentally determined. The scaling law relationships are compared to the theoretical expectations of the sticky Rouse and sticky reptation models [Macromolecules 2001, 34, 1058-1068], and both qualitative and quantitative differences are observed.
引用
收藏
页码：5465 / 5472
页数：8
相关论文
共 50 条
  • [41] Throughput scaling laws for wireless networks with fading channels
    Ebrahimi, Masoud
    Maddah-Ali, Mohammad A.
    Khandani, Amir K.
    [J]. IEEE TRANSACTIONS ON INFORMATION THEORY, 2007, 53 (11) : 4250 - 4254
  • [42] Multicast Capacity Scaling Laws for Multihop Cognitive Networks
    Wang, Cheng
    Tang, Shaojie
    Li, Xiang-Yang
    Jiang, Changjun
    [J]. IEEE TRANSACTIONS ON MOBILE COMPUTING, 2012, 11 (11) : 1627 - 1639
  • [43] Scaling laws of single polymer dynamics near attractive surfaces
    Mukherji, Debashish
    Bartels, Guido
    Mueser, Martin H.
    [J]. PHYSICAL REVIEW LETTERS, 2008, 100 (06)
  • [44] Scaling laws for solvent permeation in polymer-solvent systems
    Timmermann, EO
    [J]. ANALES DE LA ASOCIACION QUIMICA ARGENTINA, 1996, 84 (01): : 13 - 18
  • [45] Hydrogen-bonded supramolecular polymer networks
    Lange, RFM
    Van Gurp, M
    Meijer, EW
    [J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1999, 37 (19) : 3657 - 3670
  • [46] Supramolecular hydrogen-bonded polymer networks
    Litvin, AL
    Bliznyuk, VN
    Tsukruk, VV
    Valiyaveettil, S
    Kaplan, DL
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1996, 212 : 273 - POLY
  • [47] Supramolecular polymer networks: hydrogels and bulk materials
    Voorhaar, Lenny
    Hoogenboom, Richard
    [J]. CHEMICAL SOCIETY REVIEWS, 2016, 45 (14) : 4013 - 4031
  • [48] Evolution of dynamic supramolecular polymer networks for biomedicine
    Weil, Tanja
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2019, 258
  • [49] Supramolecular thermoreversible polymer networks with tunable properties
    Week, Marcus
    Nair, Kamlesh P.
    Breedveld, Victor
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2009, 237
  • [50] Supramolecular Polymer Networks: Preparation, Properties, and Potential
    Rossow, Torsten
    Seiffert, Sebastian
    [J]. SUPRAMOLECULAR POLYMER NETWORKS AND GELS, 2015, 268 : 1 - 46
12345