Synthesis and Self-Association of Organoplatinum(IV) Boronic Acids

被引：14

作者：

Safa, Muhieddine A. ^{[1
]}

Abo-Amer, Anwar ^{[1
,2
]}

Borecki, Aneta ^{[1
]}

Cooper, Benjamin F. T. ^{[1
]}

Puddephatt, Richard J. ^{[1
]}

机构：

[1] Univ Western Ontario, Dept Chem, London, ON N6A 5B7, Canada

[2] Al Al Bayt Univ, Dept Chem, Al Mafraq, Jordan

来源：

ORGANOMETALLICS | 2012年 / 31卷 / 07期

基金：

加拿大自然科学与工程研究理事会;

关键词：

HYDROGEN-BONDED NETWORKS; MOLECULAR-COMPLEXES; PLATINUM COMPLEXES; PHENYLBORONIC ACID; BONDING GROUPS; REACTIVITY; SALTS; DERIVATIVES; BINUCLEAR; CHEMISTRY;

D O I：

10.1021/om2009217

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Oxidative addition of ortho, meta, and para isomers of BrCH2C6H4B(OH)(2) to dimethylplatinum(II) complexes gave the corresponding organoplatinum(IV) boronic acids [PtBrMe2{CH2C6H4B(OH)(2)}(NN)], with the bidentate ligand NN = 4,4'-bis(ethoxycarbonyl)-2,2'-bipyridine or 2,5-bis(2-pyridyl)-1,3,4-oxadiazole. The complexes undergo self-assembly in the solid state through hydrogen bonding to give dimers, polymers, or sheet structures.

引用

页码：2675 / 2681

页数：7

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