Volumetric Properties for (Ionic Liquid plus Methanol or Ethanol or 1-Propanol + Nitromethane) at 298.15 K and Atmospheric Pressure

被引:38
|
作者
Deenadayalu, Nirmala [1 ]
Bahadur, Indra [1 ]
Hofman, Tadeusz [2 ]
机构
[1] Durban Univ Technol, Dept Chem, ZA-4000 Durban, South Africa
[2] Warsaw Univ Technol, Fac Chem, Div Phys Chem, PL-00664 Warsaw, Poland
来源
关键词
EXCESS MOLAR VOLUMES; TERNARY-SYSTEM (ETHANOL; 313.15; K; ATMOSPHERIC-PRESSURE; BINARY-SYSTEMS; IONIC LIQUIDS; DIFFERENT TEMPERATURES; MIXTURES; DENSITY; ACETATE;
D O I
10.1021/je100830b
中图分类号
O414.1 [热力学];
学科分类号
摘要
The densities of the ternary systems {1-butyl-3-methylimidazolium methyl sulfate ([BMIM](+)[MeSO4](-)) + methanol or ethanol or 1-propanol + nitromethane} were measured at the temperature 298.15 K, and the ternary excess molar. volumes, V-123(E), were calculated. The V-123(E) values are negative for all mole fractions of the ionic liquid (IL) and increase with increasing mole fraction of IL. The Cibulka equation was used to correlate the ternary excess molar volumes using the Redlich-Kister parameters for the binary systems obtained from the literature. There is a good correlation between the Cibulka equation and the experimental V-123(E) data.
引用
收藏
页码:1682 / 1686
页数:5
相关论文
共 50 条
  • [21] Liquid viscosity of binary mixtures of methanol with ethanol and 1-propanol from 273.15 to 333.15 K
    Kumagai, A
    Yokoyama, C
    INTERNATIONAL JOURNAL OF THERMOPHYSICS, 1998, 19 (01) : 3 - 13
  • [22] Liquid Viscosity of Binary Mixtures of Methanol with Ethanol and 1-Propanol from 273.15 to 333.15 K
    A. Kumagai
    C. Yokoyama
    International Journal of Thermophysics, 1998, 19 : 3 - 13
  • [23] Excess enthalpies of 2,4-pentanedione plus (methanol, plus ethanol, plus 1-propanol, and plus 2-propanol) at T = (298.15, 313.15, and 328.15) K and p = (0.1 and 10.0) MPa
    Li, Shengying
    Yan, Weidong
    Dong, Hong
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2008, 53 (01): : 194 - 198
  • [24] Excess molar enthalpies of ternary mixtures of ethanol plus 1-propanol plus tetrahydropyran or 1,4-dioxane at 298.15 K
    Tamura, K
    Bhuiyan, MMH
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2005, 50 (01): : 66 - 71
  • [25] Solubility of dimethyl fumarate in water plus (methanol, ethanol, 1-propanol) from (278.15 to 333.15) K
    Kai, Yumei
    Hu, Yonghong
    Tang, Rongrong
    Meng, Zhongbin
    Yang, Wenge
    FLUID PHASE EQUILIBRIA, 2013, 344 : 19 - 26
  • [26] Hydrogen Bonding and Molecular Aggregates in Liquid Methanol, Ethanol, and 1-Propanol
    Vrhovsek, Aleksander
    Gereben, Orsolya
    Jamnik, Andrej
    Pusztai, Laszlo
    JOURNAL OF PHYSICAL CHEMISTRY B, 2011, 115 (46): : 13473 - 13488
  • [27] Ternary liquid-liquid equilibria for (water plus terpene plus 1-propanol or 1-butanol) systems at the temperature 298.15 K
    Li, Hengde
    Tamura, Kazuhiro
    FLUID PHASE EQUILIBRIA, 2008, 263 (02) : 223 - 230
  • [28] Excess molar enthalpies of ethyl acetoacetate plus (methanol, +ethanol, +1-propanol, and +2-propanol) at T = (298.15, 313.15 and 328.15) K and p = (0.1 and 10.0) MPa
    Gao, Hui
    Li, Shengying
    Yan, Weidong
    FLUID PHASE EQUILIBRIA, 2008, 268 (1-2) : 34 - 38
  • [29] Study on volumetric measurement and correlations for MTBE+1-propanol+decane at 298.15 K and atmospheric pressure
    Mato, MM
    Cebreiro, SM
    Verdes, PV
    Pallas, AV
    Legido, JL
    Andrade, MIP
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2005, 80 (02) : 317 - 321
  • [30] Liquid-liquid equilibria at 298.15 K for ternary mixtures of methyl tert-butyl ether plus methanol (or ethanol) plus imidazolium-based ionic liquids at atmospheric pressure
    Shin, Sang Hong
    Hwang, In-Chan
    Park, So-Jin
    FLUID PHASE EQUILIBRIA, 2013, 342 : 82 - 87