The absorption spectrum and absolute absorption cross sections of acetylperoxy radicals, CH3C(O)O2 in the near IR

被引：3
|
作者：
Rolletter, Michael [1 ]
Assaf, Emmanuel [2 ,3 ]
Assali, Mohamed [2 ]
Fuchs, Hendrik [1 ]
Fittschen, Christa [2 ]
机构：
[1] Forschungszentrum Julich, Inst Energy & Climate Res, IEK 8 Troposphere, D-52428 Julich, Germany
[2] Univ Lille, PC2A Physicochim Proc Combust & Atmosphere, CNRS, UMR 8522, F-59000 Lille, France
[3] NOAA, Earth Syst Res Lab, Chem Sci Div, Boulder, CO 80305 USA
来源：
JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER | 2020年 / 245卷
基金：
欧洲研究理事会;
关键词：
RING-DOWN SPECTROSCOPY; GAS-PHASE REACTIONS; ATMOSPHERIC CHEMISTRY; PHOTOCHEMICAL DATA; PEROXY-RADICALS; SELF-REACTION; 2-NU(1) BAND; KINETICS; HO2; OH;
D O I：
10.1016/j.jqsrt.2020.106877
中图分类号：
O43 [光学];
学科分类号：
070207 ; 0803 ;
摘要：
The (A) over tilde-(X) over tilde electronic transition of acetylperoxy radicals (CH3C(O)O-2) in the near-infrared was measured at 67hPa synthetic air in the spectral ranges from 6094 cm(-1) to 6180 cm(-1) and 6420 cm(-1) to 6600 cm(-1). CH3C(O)O-2 radicals were generated by the pulsed photolysis of a acetaldehyde/Cl-2/O-2 mixture at 351 nm and subsequently measured by time-resolved continuous-wave cavity ring-down spectroscopy (cw-CRDS). The absorption cross sections of eight discrete absorption lines were determined relative to the absorption cross section of HO2, which has previously been reported. The strongest absorption cross section was found at 6510.73 cm(-1) and was determined to be (4.9 +/- 2.5) 10(-20) cm(2). (C) 2020 The Authors. Published by Elsevier Ltd.
引用
收藏
页数：6
相关论文
共 50 条
  • [21] REACTION OF OH RADICALS WITH CH3C(O)H AND CF3C(O)H
    FRANCISCO, JS
    JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1992, 88 (14): : 1943 - 1947
  • [22] Atmospheric chemistry of acetone:: Kinetic study of the CH3C(O)CH2O2+NO/NO2 reactions and decomposition of CH3C(O)CH2O2NO2
    Sehested, J
    Christensen, LK
    Nielsen, OJ
    Bilde, M
    Wallington, TJ
    Schneider, WF
    Orlando, JJ
    Tyndall, GS
    INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1998, 30 (07) : 475 - 489
  • [23] Absorption cross-sections of atmospheric constituents: NO2, O2, and H2O
    Christian Hermans
    Ann C. Vandaele
    Michel Carleer
    Sophie Fally
    Réginald Colin
    Alain Jenouvrier
    Bernard Coquart
    Marie-France Mérienne
    Environmental Science and Pollution Research, 1999, 6 : 151 - 158
  • [24] Absorption cross-sections of atmospheric constituents:: NO2, O2, and H2O
    Hermans, C
    Vandaele, AC
    Carleer, M
    Fally, S
    Colin, R
    Jenouvrier, A
    Coquart, B
    Mérienne, MF
    ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH, 1999, 6 (03) : 151 - 158
  • [25] Density functional theory study of the reaction paths of reactions of CH3C(O)O2 radicals with HO2 in the gas phase
    Zhou Yuzhi
    Zhang Shaowen
    Li Qianshu
    PROGRESS IN NATURAL SCIENCE-MATERIALS INTERNATIONAL, 2006, 16 (12) : 1269 - 1274
  • [26] Density functional theory study of the reaction paths of reactions of CH3C(O)O2 radicals with HO2 in the gas phase
    ZHOU Yuzhi~ 1
    2. Beijing Institute of Education
    Progress in Natural Science, 2006, (12) : 1269 - 1274
  • [27] CRYSTAL AND MOLECULAR-STRUCTURES OF THE ACETYLACETONATE DERIVATIVES [SE(CH3C(O)CC(O)CH3)]2 AND [PHSE]2[CH3C(O)CC(O)CH3]
    ADRIEN, RJ
    GABLE, RW
    HOSKINS, BF
    DAKTERNIEKS, D
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 359 (01) : 33 - 39
  • [28] THE BANDS OF THE [O2]2 COMPLEX IN THE NEAR-INFRARED ABSORPTION SPECTRUM OF THE ATMOSPHERE
    DIANOVKLOKOV, VI
    OPTIKA I SPEKTROSKOPIYA, 1964, 17 (01): : 146 - 149
  • [29] Thermochemistry and kinetics of the 2-butanone-4-yl CH3C(=O)CH2CH2• + O2 reaction system
    Sebbar, N.
    Bozzelli, J. W.
    Trimis, D.
    Bockhorn, H.
    INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 2019, 51 (08) : 541 - 562
  • [30] Ultraviolet absorption spectrum and cross-sections of ethynyl (C2H) radicals
    Fahr, A
    JOURNAL OF MOLECULAR SPECTROSCOPY, 2003, 217 (02) : 249 - 254
12345