Conductive metal and covalent organic frameworks for electrocatalysis: design principles, recent progress and perspective

被引:30
|
作者
Wang, Jinyan [1 ]
Hu, Hongyin [1 ]
Lu, Shuanglong [1 ]
Hu, Jundie [2 ]
Zhu, Han [1 ]
Duan, Fang [1 ]
Du, Mingliang [1 ]
机构
[1] Jiangnan Univ, Sch Chem & Mat Engn, Key Lab Synthet & Biol Colloids, Minist Educ, Wuxi 214122, Jiangsu, Peoples R China
[2] Suzhou Univ Sci & Technol, Sch Mat Sci & Engn, Suzhou 215009, Peoples R China
基金
中国国家自然科学基金; 中国博士后科学基金;
关键词
OXYGEN REDUCTION; ELECTRICAL-CONDUCTIVITY; RENEWABLE ENERGY; CO2; EVOLUTION; CATALYSIS; ELECTROREDUCTION; SITES;
D O I
10.1039/d1nr06197f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Metal and covalent organic frameworks (MOFs/COFs) are emerging promising candidates in the field of catalysts due to their porous nature, chemically well-defined active sites and structural diversity. However, they are typically provided with poor electrical conductivity, which is insufficient for them to work as satisfying electrocatalysts. Designing and fabricating MOFs/COFs with high conductivity presents a new avenue towards special electrochemical reactions. This minireview firstly highlighted the origin and design principles of conductive MOFs/COFs for electrocatalysis on the basis of typical charge transfer mechanisms, that is "through space", "extended conjugation" and "through bond". An overview of conductive MOFs/COFs used in the electrocatalytic carbon dioxide reduction reaction (CO2RR), water splitting and the oxygen reduction reaction (ORR) was then made to track the very recent progress. In the final remarks, the present challenges and perspectives for the use of conductive MOFs/COFs as electrocatalysts including their structural optimization, feasible applications and structure-activity correlation are proposed.
引用
收藏
页码:277 / 288
页数:12
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