Synthesis of 4-sulfonatooxy-2,2,6,6-tetramethylpiperidine-1-yloxyl derivatives for investigation of ionic liquids

被引：23

作者：

Strehmel, Veronika ^{[1
]}

Rexhausen, Hans ^{[1
]}

Strauch, Peter ^{[2
]}

机构：

[1] Univ Potsdam, Inst Chem Appl Polymer Chem, D-14476 Potsdam, Germany

[2] Univ Potsdam, Inst Chem Inorgan Chem, D-14476 Potsdam, Germany

来源：

TETRAHEDRON LETTERS | 2008年 / 49卷 / 04期

关键词：

spin probes; ESR spectroscopy; nitroxides; ionic liquids;

D O I：

10.1016/j.tetlet.2007.11.150

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Direct sulfonation of 4-hydroxy-2,2,6,6-tetramethylpiperidine-1-yloxyl using chlorosulfuric acid trimethylsilylester results in 4-sulfonatooxy-2,2,6,6-tetra-methylpiperidine- 1-yloxyl in 94% yield that is the basis for the synthesis of potassium 4-sulfonatooxy-2,2,6,6-tetramethylpiperidine-1-yloxyl and sodium 4-sulfonatooxy-2,2,6,6-tetramethylpiperidine-1-yloxyl. These nitroxides can be employed as spin probes to investigate properties of ionic liquids in the molecular domain. (c) 2007 Elsevier Ltd. All rights reserved.

引用

页码：586 / 588

页数：3

共 50 条

[41] 2,2,6,6-TETRAMETHYLPIPERIDINE-1-OXYL-4-YL ALPHA-D-GLUCOPYRANOSIDE
HEMPEL, A
CAMERMAN, N
HAMODRAKAS, SJ
OTTENSMEYER, FP
TROGANIS, A
STASSINOPOULOU, CI
CAMERMAN, A
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1993, 49 : 298 - 300
[42] EFFECT OF 4-SUBSTITUTED DERIVATIVES OF 2,2,6,6-TETRAMETHYLPIPERIDINE-1-OXYL ON THE OXYHEMOGLOBIN AUTOOXIDATION IN MAN IN ALKALI MEDIUM - NEW SPIN MARKING - 2,2,6,6-TETRAMETHYL-4-BROM-4-NITROPIPERIDINE-1-OXYL
MYSHKIN, AE
KONYAEVA, VS
ZHURNAL OBSHCHEI KHIMII, 1983, 53 (09): : 2131 - 2139
[43] CONFORMATION OF THE PIPERIDINE RING .4. INVESTIGATIONS OF 4-TERT-BUTYL-4-HYDROXY-2,2,6,6-TETRAMETHYLPIPERIDINE DERIVATIVES
CYGLER, M
MARKOWICZ, T
SKOLIMOWSKI, J
SKOWRONSKI, R
JOURNAL OF MOLECULAR STRUCTURE, 1980, 68 (NOV) : 161 - 171
[44] Influence of the nature of solvent and substituents on the oxidation potential of 2,2,6,6-tetramethylpiperidine 1-oxyl derivatives
Mendkovich, A. S.
Luzhkov, V. B.
Syroeshkin, M. A.
Sen, V. D.
Khartsii, D. I.
Rusakov, A. I.
RUSSIAN CHEMICAL BULLETIN, 2017, 66 (04) : 683 - 689
[45] Influence of the nature of solvent and substituents on the oxidation potential of 2,2,6,6-tetramethylpiperidine 1-oxyl derivatives
A. S. Mendkovich
V. B. Luzhkov
M. A. Syroeshkin
V. D. Sen´
D. I. Khartsii
A. I. Rusakov
Russian Chemical Bulletin, 2017, 66 : 683 - 689
[46] Diffusion of 2,2,6,6-tetramethylpiperidine 1-oxyl derivatives of variable hydrophobicity in tropocollagen I solution
Liu, Chi Kin
Valle, Judith
Slowinska, Katarzyna
BIOELECTROCHEMISTRY, 2008, 74 (01) : 195 - 200
[47] Explosion of 4-acetylamino-2,2,6,6-tetramethylpiperidine-1-oxoammonium perchlorate and replacement by tetrafluoroborate
Bobbitt, JM
MOLECULES, 1999, 4 (09) : M102 - U4
[48] ELECTRODE-REACTIONS OF NITROXIDE RADICALS .9. ANODIC OXIDATIONS OF 4-HYDROXYIMINO-2,2,6,6-TETRAMETHYLPIPERIDINE-1-OXYL AND 4-[(AMINOCARBONYL)-HYDRAZONE]-2,2,6,6-TETRAMETHYLPIPERIDINE-1-OXYL IN WATER SOLUTIONS
DEILARDUYA, JIM
KRZYCZMONIK, P
SCHOLL, H
GRABOWSKI, G
ELECTROANALYSIS, 1991, 3 (03) : 233 - 237
[49] Synthesis and application of new combined 2,2,6,6-tetramethylpiperidine-2-hydroxybenzophenone 1,3,5-triazine derivatives as photostabilizers for polymer materials
Bojinov, V
Grabchev, I
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2002, 146 (03) : 199 - 205
[50] Dehydrogenation of nitro derivatives of bibenzyl to corresponding nitro stilbene with dioxygen catalyzed by 2,2,6,6-tetramethylpiperidine-1-oxyl
Lu, Tingting
Lu, Ming
JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2012, 9 (06) : 971 - 975

← 1 2 3 4 5 →