The role of pyruvic acid as starting material in some organic reactions in the presence of SBA-Pr-SO3H nanocatalyst

被引：11
|
作者：
Ziarani, Ghodsi Mohammadi [1 ]
Gholamzadeh, Parisa [1 ]
Badiei, Alireza [2 ]
Vavsari, Vaezeh Fathi [1 ]
机构：
[1] Alzahra Univ, Dept Chem, Vanak Sq, Tehran, Iran
[2] Univ Tehran, Sch Chem, Coll Sci, Tehran, Iran
来源：
RESEARCH ON CHEMICAL INTERMEDIATES | 2018年 / 44卷 / 01期
关键词：
Pyruvic acid; SBA-Pr-SO3H; Oxindole; Niementowski reaction; Ugi reaction; ONE-POT SYNTHESIS; MESOPOROUS SILICA; GREEN SYNTHESIS; EFFICIENT SYNTHESIS; DERIVATIVES; CATALYST; ALKALOIDS; SBA-15; QUINAZOLIN-4(3H)-ONES; NANOREACTOR;
D O I：
10.1007/s11164-017-3103-4
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Pyruvic acid contains three different reactive positions: -COOH, ketone carbonyl and methyl groups. Correspondingly, pyruvic acid was applied as starting material in the modified Niementowski reaction and Aldol condensation using SBA-Pr-SO3H as an efficient nanocatalyst. Aldol condensation of pyruvic acid and oxindole provided a new oxindol-based carboxylic acid which was subsequently used in the Ugi four-component reaction. Moreover, through the modified Niementowski reaction of pyruvic acid, new derivatives of quiazoline were produced in the presence of SBA-Pr-SO3H. The obtained products are important due to their potentially biological active skeletons.
引用
收藏
页码：277 / 288
页数：12
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